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运用电子鼻和气相色谱/质谱联用技术对不同保鲜方法下的新鲜鲟鱼挥发性化合物进行分析。

Analysis of volatile compounds in fresh sturgeon with different preservation methods using electronic nose and gas chromatography/mass spectrometry.

作者信息

Hou Wenfu, Han Qianhui, Gong Heng, Liu Wen, Wang Hongxun, Zhou Min, Min Ting, Pan Siyi

机构信息

College of Food Science and Technology, Huazhong Agricultural University 1st Shizishan Road Wuhan Hubei 430070 P. R. China

College of Food Science and Engineering, Wuhan Polytechnic University Wuhan Hubei 430023 P. R. China.

出版信息

RSC Adv. 2019 Nov 28;9(67):39090-39099. doi: 10.1039/c9ra06287d. eCollection 2019 Nov 27.

Abstract

Contamination of microorganisms causes a rapid deterioration in the quality of fresh sturgeon meat, which results in the shortening of the shelf-life and increase in the health risk. In this paper, two preservation treatments based on microbial control were considered. During the chilling storage (0-6 days) period, the sensory analysis and the volatile compound (VOC) evaluation were performed by electronic nose and SPME-GC/MS. Results showed that washing with acidic oxidized electrolyzed water and the addition of ε-PL influences the sensitive VOCs of the fresh sturgeon by inhibiting the spoilage of microbes or introducing the chemical agents like free chlorine and reactive oxygen species. Furthermore, GC/MS analysis detected more than 40 kinds of VOCs, mainly aldehydes and ketones, in the fresh sturgeon during the chilling storage period. The relative content of heptanal, nonanal, and acetophenone increased linearly with the storage time in all the groups, where of all the groups was larger than 0.9. However, the content of hexanal and octanal decreased simultaneously. This indicated that the present work discovered the potential biomarkers acting as indicators for rapidly evaluating the quality of sturgeon products.

摘要

微生物污染会导致新鲜鲟鱼肉的品质迅速下降,从而缩短其货架期并增加健康风险。本文考虑了两种基于微生物控制的保鲜处理方法。在冷藏储存(0 - 6天)期间,通过电子鼻和固相微萃取-气相色谱/质谱联用仪进行感官分析和挥发性化合物(VOC)评估。结果表明,用酸性氧化电解水清洗和添加ε-聚赖氨酸通过抑制微生物腐败或引入游离氯和活性氧等化学物质来影响新鲜鲟鱼的敏感挥发性有机化合物。此外,气相色谱/质谱联用分析在冷藏储存期间的新鲜鲟鱼中检测到40多种挥发性有机化合物,主要是醛类和酮类。在所有组中,庚醛、壬醛和苯乙酮的相对含量随储存时间呈线性增加,所有组的相关系数均大于0.9。然而,己醛和辛醛的含量同时下降。这表明本研究发现了可作为快速评估鲟鱼产品质量指标的潜在生物标志物。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d118/9075984/ca8d83e5f651/c9ra06287d-f1.jpg

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