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阳离子和阴离子掺杂剂掺入聚合物本体异质结太阳能电池的ZnO电子传输层中的作用。

The role of cation and anion dopant incorporated into a ZnO electron transporting layer for polymer bulk heterojunction solar cells.

作者信息

Kim Soyeon, Jeong Jaehoon, Hoang Quoc Viet, Han Joo Won, Prasetio Adi, Jahandar Muhammad, Kim Yong Hyun, Cho Shinuk, Chan Lim Dong

机构信息

Surface Technology Division, Korea Institute of Materials Science (KIMS) 797 Changwondaero, Seongsan-gu Changwon Gyeongnam 51508 Republic of Korea

Vietnam-Korea Technological Innovation Center, Directorate for Standards, Metrology and Quality (STAMEQ) No. 8 Hoang Quoc Viet, Cau Giay Ha Noi Vietnam.

出版信息

RSC Adv. 2019 Nov 19;9(65):37714-37723. doi: 10.1039/c9ra06974g.

DOI:10.1039/c9ra06974g
PMID:35541802
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9075736/
Abstract

Doping is a widely-implemented strategy for enhancing the inherent electronic properties of charge transport layers in photovoltaic devices. A facile solution-processed zinc oxide (ZnO) and various cation and anion-doped ZnO layers were synthesized the sol-gel method and employed as electron transport layers (ETLs) for inverted polymer solar cells (PSCs). The results indicated that all PSCs with doped ZnO ETLs exhibited better photovoltaic performance compared with the PSCs with a pristine ZnO ETL. By exploring the role of various anion and cation dopants (three compounds with the same Al cation: Al(acac), Al(NO), AlCl and three compounds with the same Cl anion: NHCl, MgCl, AlCl), we found that the work function changed to favor electronic extraction only when the Cl anion was involved. In addition, the conductivity of ZnO was enhanced more with the Al cation. Therefore, in inverted solar cells, doping with Al and Cl delivered the best power conversion efficiency (PCE). The maximum PCE of 10.38% was achieved from the device with ZnO doped with Al and Cl.

摘要

掺杂是一种广泛应用的策略，用于增强光伏器件中电荷传输层的固有电子特性。采用溶胶-凝胶法合成了一种简便的溶液处理氧化锌（ZnO）以及各种阳离子和阴离子掺杂的ZnO层，并将其用作倒置聚合物太阳能电池（PSC）的电子传输层（ETL）。结果表明，与具有原始ZnO ETL的PSC相比，所有具有掺杂ZnO ETL的PSC均表现出更好的光伏性能。通过探索各种阴离子和阳离子掺杂剂（三种具有相同Al阳离子的化合物：Al(acac)、Al(NO)、AlCl和三种具有相同Cl阴离子的化合物：NHCl、MgCl、AlCl）的作用，我们发现只有当涉及Cl阴离子时，功函数才会发生变化以利于电子提取。此外，Al阳离子对ZnO电导率的增强作用更大。因此，在倒置太阳能电池中，Al和Cl掺杂实现了最佳的功率转换效率（PCE）。掺杂Al和Cl的ZnO器件实现了10.38%的最大PCE。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/1a72097f8858/c9ra06974g-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/0d8e0e29d9f4/c9ra06974g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/7571312e0c57/c9ra06974g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/846b93b1f5be/c9ra06974g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/2f241c32eab1/c9ra06974g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/8c83ba5c3f03/c9ra06974g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/fb72c93addf9/c9ra06974g-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/1a72097f8858/c9ra06974g-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/0d8e0e29d9f4/c9ra06974g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/7571312e0c57/c9ra06974g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/846b93b1f5be/c9ra06974g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/2f241c32eab1/c9ra06974g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/8c83ba5c3f03/c9ra06974g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/fb72c93addf9/c9ra06974g-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13cc/9075736/1a72097f8858/c9ra06974g-f7.jpg

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