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一类高效的双氮杂环卡宾盐：在温和反应条件下钯催化反应中的应用。

An efficient class of bis-NHC salts: applications in Pd-catalyzed reactions under mild reaction conditions.

作者信息

Chiu Chien-Cheng, Chiu Hui-Tzu, Lee Dong-Sheng, Lu Ta-Jung

机构信息

Department of Chemistry, National Chung-Hsing University Taichung 402 Taiwan

出版信息

RSC Adv. 2018 Jul 24;8(46):26407-26415. doi: 10.1039/c8ra04094j. eCollection 2018 Jul 19.

DOI:10.1039/c8ra04094j
PMID:35541928
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9083023/
Abstract

This study describes an efficient class of bis-N-heterocyclic carbene (bis-NHC) salts that can be easily made from commercially available and inexpensive starting materials. The application of these salts to Pd-catalyzed reactions is described. The palladium (Pd) catalyst generated was highly effective under mild reaction conditions.

摘要

本研究描述了一类高效的双-N-杂环卡宾（bis-NHC）盐，它们可以很容易地由市售且廉价的起始原料制备而成。文中还描述了这些盐在钯催化反应中的应用。所生成的钯（Pd）催化剂在温和的反应条件下具有很高的活性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1893/9083023/e4deb0c0be34/c8ra04094j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1893/9083023/e1892ea103a3/c8ra04094j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1893/9083023/abf7c9e3fc0a/c8ra04094j-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1893/9083023/c9e417bdb90f/c8ra04094j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1893/9083023/e4deb0c0be34/c8ra04094j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1893/9083023/e1892ea103a3/c8ra04094j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1893/9083023/abf7c9e3fc0a/c8ra04094j-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1893/9083023/c9e417bdb90f/c8ra04094j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1893/9083023/e4deb0c0be34/c8ra04094j-f3.jpg

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Recent advances in carbon-carbon bond-forming reactions involving homoenolates generated by NHC catalysis.涉及由NHC催化产生的高烯醇盐的碳-碳键形成反应的最新进展。
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Organocatalysis by N-heterocyclic carbenes.氮杂环卡宾的有机催化作用。
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Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes.对BINAP连接的钯配合物催化芳基卤化物胺化反应机理的重新评估。
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