通过一锅法铃木-宫浦偶联反应合成的1,3-亚苯基桥连萘轮以及六聚体与C的配合物

1,3-Phenylene-bridged naphthalene wheels synthesized by one-pot Suzuki-Miyaura coupling and the complex of the hexamer with C.

作者信息

Mei Peifeng, Matsumoto Akinobu, Hayashi Hironobu, Suzuki Mitsuharu, Aratani Naoki, Yamada Hiroko

机构信息

Graduate School of Science and Technology, Nara Institute of Science and Technology (NAIST) Takayama-cho Ikoma Nara 630-0192 Japan

出版信息

RSC Adv. 2018 Jun 7;8(37):20872-20876. doi: 10.1039/c8ra03601b. eCollection 2018 Jun 5.

A large 1,3-phenylene-bridged hexameric naphthalene wheel N6 and a heptameric wheel N7 were synthesized simply by Suzuki-Miyaura coupling one-pot reaction from monomers. We could control the distribution of N6 and N7 the reaction conditions. The hexameric wheel structure was revealed by X-ray diffraction analysis. The wheel N6 exhibited C encapsulation ability in the solid state, which was also confirmed by single crystal X-ray analysis.