芘齐聚物的环化：环己-1,3-芘。
Cyclization of Pyrene Oligomers: Cyclohexa-1,3-pyrenylene.
机构信息
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany).
出版信息
Angew Chem Int Ed Engl. 2016 Jan 4;55(1):418-21. doi: 10.1002/anie.201508180. Epub 2015 Nov 6.
PMID:26546101
Abstract
First synthesis of the macrocycle cyclohexa(1,3-pyrenylene) is achieved in six steps starting with pyrene, leading to a non-aggregating highly twisted blue-light-emitting material. The cyclodehydrogenation of the macrocycle offers a promising synthesis route to holey-nanographene.
摘要
首次通过六步反应从苝出发合成了大环环己六（1,3-并苝），得到了一种不聚集的高度扭曲的蓝光发射材料。该大环的环脱氢反应为制备多孔纳米石墨烯提供了一条很有前途的合成路线。
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