New highly hydrated cellulose microfibrils with a tendril helical morphology extracted from agro-waste material: application to removal of dyes from waste water.

Cocoa bean shells (CBS) are a by-product of the cocoa bean processing industry. They represent 12-20 wt% of dry cocoa beans, after having been separated from these by a roasting process. CBS often end up as a waste product which contains around 34 wt% of cellulose. The transformation of this waste into valuable and marketable products would help to improve waste disposal. Indeed, the large annual production of this waste makes it a sustainable and renewable bio-source for the production of chemicals and fibers for advanced applications. In this work, new cellulose microfibrils (CMFs) with a tendril helical morphology and highly hydrated gel-like behavior were successfully extracted from CBS waste using a controlled chemical extraction process. During this study, several physico-chemical characterizations were carried out in order to identify the properties of each of the products at different stages of treatment. Microscopic observations show that the extracted CMFs have a tendril helical shape like climbing plant tendrils. Due to this special morphology, the extracted CMFs show a highly hydrated state forming a gel network without additional modifications. The as-extracted CMFs were used as adsorbent material for the removal of methylene blue from concentrated aqueous solution, as an application to wastewater treatment for the removal of basic dyes. Swelling properties, adsorption kinetics and isotherms were carried out in batch experiments. The results indicated that the CMFs have a high swelling capacity (190%). The pseudo second order model can be effectively used to evaluate the adsorption kinetics and the adsorption isotherms can also be described well by the Langmuir isotherm model with a maximum adsorption capacity of 381.68 mg g. Thus, the as-extracted CMFs with unique characteristics have the potential to be used as efficient adsorbent material for the removal of different cationic dyes from industrial wastewater.