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钌（II）配位的双层倍半硅氧烷的合成与光化学反应

Synthesis and photochemical response of Ru(ii)-coordinated double-decker silsesquioxane.

作者信息

Kucuk Asuman Celik, Matsui Jun, Miyashita Tokuji

机构信息

Metallurgical and Materials Engineering, Marmara University Gostepe Campus 34722 Istanbul Turkey

Department of Material and Biological Chemistry, Yamagata University 1-4-12, Kojirakawamachi Yamagata 990-8560 Japan

出版信息

RSC Adv. 2018 Jan 9;8(4):2148-2156. doi: 10.1039/c7ra12290j. eCollection 2018 Jan 5.

DOI:10.1039/c7ra12290j
PMID:35542610
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9077204/
Abstract

A double-decker silsesquioxane based bis(terpyridine) ruthenium(ii) complex (2Tpy/Ru-DDSQ), a member of the polyhedral oligomeric silsesquioxane (POSS) class, has been synthesized. Its structure has been characterized using comprehensive techniques such as nuclear magnetic resonance (H NMR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and UV-visible spectroscopy. This work not only deals with the synthesis of 2Tpy/Ru-DDSQ but also provides the first comprehensive investigation based on the photoluminescence and electrochemical features of a POSS member. With this structure, an efficient anodic photocurrent response has been obtained. This result has been attributed to the perfect arrangement of ruthenium(ii)-bis(terpyridine) (tpy) ([Ru(Tpy)]) moieties in the DDSQ nano building blocks. Therefore, 2Tpy/Ru-DDSQ can be considered as a promising candidate for the development of new generation photosensitizers.

摘要

一种基于双甲板倍半硅氧烷的双（三联吡啶）钌（II）配合物（2Tpy/Ru-DDSQ），属于多面体低聚倍半硅氧烷（POSS）类的一员，已被合成。其结构已通过核磁共振（H NMR）光谱、X射线光电子能谱（XPS）和紫外可见光谱等综合技术进行了表征。这项工作不仅涉及2Tpy/Ru-DDSQ的合成，还基于POSS成员的光致发光和电化学特性进行了首次全面研究。基于这种结构，获得了高效的阳极光电流响应。该结果归因于DDSQ纳米结构单元中钌（II）-双（三联吡啶）（tpy）（[Ru(Tpy)]）部分的完美排列。因此，2Tpy/Ru-DDSQ可被视为新一代光敏剂开发的有前途的候选物。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49fb/9077204/4ab68157b2eb/c7ra12290j-f9.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49fb/9077204/4ab68157b2eb/c7ra12290j-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49fb/9077204/913e181e3c68/c7ra12290j-s1.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49fb/9077204/729364c02bdf/c7ra12290j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49fb/9077204/e67feeb014c5/c7ra12290j-c1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49fb/9077204/c1074da8f808/c7ra12290j-f6.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49fb/9077204/4ab68157b2eb/c7ra12290j-f9.jpg

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