Yang Longbo, Luo Jiajun, Gao Liang, Song Boxiang, Tang Jiang
Wuhan National Laboratory for Optoelectronics (WNLO) and School of Optical and Electronic Information, Huazhong University of Science and Technology (HUST), 1037 Luoyu Road, Wuhan, Hubei 430074, China.
Optics Valley Laboratory, 1037 Luoyu Road, Wuhan, Hubei 430074, China.
J Phys Chem Lett. 2022 May 19;13(19):4365-4373. doi: 10.1021/acs.jpclett.2c00927. Epub 2022 May 11.
With the rapid development of the panel display market, demand for efficient light emitters as active layers in electroluminescence (EL) devices has significantly increased. Luminescent inorganic lanthanide compounds (ILCs) with a characteristic f-d transition are particularly preferred for EL devices because of their high photoluminescent quantum yield, short excited-state lifetime, tunable emission spectra, and high thermal stability. In this Perspective, we first present an overview of inorganic lanthanide compounds with an emphasis on the mechanisms and characteristics of f-d emission. Then, the comprehensive advances of lanthanide element-doped inorganic compounds for EL study in recent decades are summarized. Moreover, the recent progress in directly employing ILCs for EL applications and rational improvement strategies in EL performance are highlighted. Last, we summarize the current challenges and opportunities of ILC-based EL devices as well as future improvement directions.
随着平板显示市场的快速发展,对作为电致发光(EL)器件有源层的高效发光体的需求显著增加。具有特征性f-d跃迁的发光无机镧系化合物(ILCs)因其高光致发光量子产率、短激发态寿命、可调发射光谱和高热稳定性,在EL器件中尤为受青睐。在这篇展望文章中,我们首先概述无机镧系化合物,重点介绍f-d发射的机制和特性。然后,总结近几十年来镧系元素掺杂无机化合物用于EL研究的全面进展。此外,突出了直接将ILCs用于EL应用的最新进展以及EL性能的合理改进策略。最后,我们总结了基于ILCs的EL器件当前面临的挑战和机遇以及未来的改进方向。