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非共价锚定在单壁碳纳米管上的取代金属酞菁氯传感特性的定制。

Tailoring of the chlorine sensing properties of substituted metal phthalocyanines non-covalently anchored on single-walled carbon nanotubes.

作者信息

Sharma Anshul Kumar, Mahajan Aman, Kumar Subodh, Debnath A K, Aswal D K

机构信息

Material Science Laboratory, Department of Physics, Guru Nanak Dev University Amritsar 143005 India

Department of Chemistry, Guru Nanak Dev University Amritsar 143005 India.

出版信息

RSC Adv. 2018 Sep 21;8(57):32719-32730. doi: 10.1039/c8ra05529g. eCollection 2018 Sep 18.

DOI:10.1039/c8ra05529g
PMID:35547684
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9086368/
Abstract

To investigate how central metal tunes the synergetic interactions between substituted metallo-phthalocyanine and single-walled carbon nanotubes in enhancing the gas sensing properties, a comparative study has been performed by varying the central metal ion in fluorinated metal phthalocyanines and single-walled carbon nanotube hybrid. Hybrids of metal(ii)-1,2,3,4,8,9,10,11,15,16,17,18-24,25-hexa-decafluoro-29,31-phthalocyanine/single-walled carbon nanotube (FMPc/SWCNTs-COOH, where M = Co, Zn) have been synthesized through π-π stacking interactions using the solution route. Spectroscopic (FT-IR, UV-vis, XPS and Raman), electron microscopic (TEM and FE-SEM) and TGA investigations have confirmed the successful functionalization and interaction of SWCNTs-COOH with FMPc. Parts per billion (ppb) level Cl-selective chemiresistive gas sensors have been fabricated on glass substrates with precoated gold electrodes by using these hybrids. The responses of various FMPc/SWCNTs-COOH sensors have demonstrated the central metal ion-dependence in the sensitivity of Cl.

摘要

为了研究中心金属如何调节取代金属酞菁与单壁碳纳米管之间的协同相互作用以增强气敏性能，通过改变氟化金属酞菁和单壁碳纳米管杂化物中的中心金属离子进行了一项对比研究。通过溶液法利用π-π堆积相互作用合成了金属（II）-1,2,3,4,8,9,10,11,15,16,17,18-24,25-十六氟-29,31-酞菁/单壁碳纳米管（FMPc/SWCNTs-COOH，其中M = Co，Zn）的杂化物。光谱（FT-IR、UV-vis、XPS和拉曼）、电子显微镜（TEM和FE-SEM）以及TGA研究证实了SWCNTs-COOH与FMPc的成功功能化和相互作用。使用这些杂化物在预涂有金电极的玻璃基板上制备了十亿分之一（ppb）级的Cl选择性化学电阻式气体传感器。各种FMPc/SWCNTs-COOH传感器的响应表明了对Cl灵敏度的中心金属离子依赖性。

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J Mater Chem B. 2014 Nov 7;2(41):7141-7148. doi: 10.1039/c4tb01038h. Epub 2014 Sep 17.
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Electrical gas sensors based on structured organic ultra-thin films and nanocrystals on solid state substrates.基于固态衬底上结构化有机超薄膜和纳米晶体的电气气体传感器。
Nanoscale Horiz. 2016 Sep 15;1(5):383-393. doi: 10.1039/c6nh00040a. Epub 2016 May 26.
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Nanomaterials (Basel). 2021 Oct 27;11(11):2861. doi: 10.3390/nano11112861.
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4
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