五氧化二磷/金属氯化物介导果糖高效简便催化转化为5-羟甲基糠醛。
Phosphorus pentoxide/metal chloride mediated efficient and facile catalytic conversion of fructose into 5-hydroxymethylfurfural.
作者信息
Jia Songyan, He Xinjun, Ma Jiao, Xu Zhanwei, Wang Kangjun, Zhang Z Conrad
机构信息
College of Chemical Engineering, Shenyang University of Chemical Technology Shenyang Liaoning 110142 China
State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences Dalian Liaoning 116023 China
出版信息
RSC Adv. 2018 Sep 19;8(57):32533-32537. doi: 10.1039/c8ra07027j. eCollection 2018 Sep 18.
Phosphorus pentoxide (PO)/metal chloride mixtures could significantly improve 5-HMF yield and selectivity for the catalytic conversion of fructose under mild conditions, whereas neither PO nor tested metal chloride alone gave reasonable performances. A maximum 5-HMF yield of 75% with ∼85% selectivity could be achieved within 30 min at 80 °C.
五氧化二磷（PO）/金属氯化物混合物能够在温和条件下显著提高果糖催化转化制备5-羟甲基糠醛（5-HMF）的产率和选择性，而单独使用PO或所测试的金属氯化物均无法获得理想的效果。在80℃下30分钟内可实现最高75%的5-HMF产率和约85%的选择性。
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