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氧化碳纳米管作为导电碳纳米管柔性涂层中的双域协同稳定剂。

Oxidised carbon nanotubes as dual-domain synergetic stabilizers in electroconductive carbon nanotube flexible coatings.

作者信息

Herman Artur P, Boncel Sławomir

机构信息

Silesian University of Technology, Department of Organic Chemistry, Bioorganic Chemistry and Biotechnology Krzywoustego 4 44-100 Gliwice Poland

Wrocław University of Science and Technology, Faculty of Fundamental Problems of Technology, Department of Experimental Physics Wybrzeże Wyspiańskiego 27 50-370 Wrocław Poland.

出版信息

RSC Adv. 2018 Aug 31;8(54):30712-30716. doi: 10.1039/c8ra05902k. eCollection 2018 Aug 30.

Abstract

We report that combining oxidised carbon nanotubes (O-CNTs) and pristine CNTs may be the answer for more electroconductive composites. Short (<1 μm) oxidised multi-wall CNTs (O-MWCNTs) acted as an unobvious and excellent conductivity enhancer in MWCNT-based composite thin films. 'Blending' O-MWCNTs (1.5 wt%) with 250 μm-long MWCNTs (98.5 wt%), both of well-defined morphology and physicochemistry, led to a 3- and 26-fold increase in specific conductivity as compared to purely MWCNT- or purely O-MWCNT-based thin films, respectively. We explain the enhanced conductivity by the effect of a dual-domain structure of O-MWCNTs. The scale-up method, screen-printing, opens a route to application in textronics ( electrical and electronic textiles) and hence targets for medicine, civil/military engineering, wellness, .

摘要

我们报道,将氧化碳纳米管(O-CNTs)与原始碳纳米管相结合可能是制备更具导电性复合材料的答案。短(<1μm)的氧化多壁碳纳米管(O-MWCNTs)在基于MWCNT的复合薄膜中作为一种不明显但出色的导电性增强剂。将具有明确形态和物理化学性质的1.5 wt%的O-MWCNTs与250μm长的MWCNTs(98.5 wt%)“混合”,与纯MWCNT基或纯O-MWCNT基薄膜相比,分别使比电导率提高了3倍和26倍。我们通过O-MWCNTs的双域结构效应来解释导电性的增强。放大方法——丝网印刷,为在电子织物(电气和电子纺织品)中的应用开辟了一条途径,因此可用于医学、民用/军事工程、健康等领域。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a282/9086579/a1be89421e9c/c8ra05902k-f1.jpg

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