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磁性生物聚合物作为多组分反应催化剂应用的最新进展。

Recent advances in the application of magnetic bio-polymers as catalysts in multicomponent reactions.

作者信息

Kheilkordi Zohreh, Mohammadi Ziarani Ghodsi, Mohajer Fatemeh, Badiei Alireaza, Sillanpää Mika

机构信息

Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University Tehran Iran 1993893979

School of Chemistry, College of Science, University of Tehran Tehran Iran.

出版信息

RSC Adv. 2022 Apr 26;12(20):12672-12701. doi: 10.1039/d2ra01294d. eCollection 2022 Apr 22.

Abstract

Magnetic nanoparticles have attracted significant attention due to their high surface area and superparamagnetic properties. Bio-polymers composed of polysaccharides including alginate, cellulose, glucose, dextrin, chitosan, and starch can be immobilized on magnetic nanoparticles. Bio-polymers can be obtained from natural sources, such as plants, tunicates, algae, and bacteria. Bio-polymers obtained from natural sources have attracted attention due to their various properties including efficient functional groups, non-toxicity, low cost, availability, and biocompatibility. According to the targets of "green chemistry", the application of bio-polymers is effective in reducing pollution. Furthermore, they are excellent agents for the functionalization of magnetic nanoparticles to yield nanomagnetic bio-polymers, which can be applied as recoverable and eco-friendly catalysts in multicomponent reactions.

摘要

磁性纳米颗粒因其高比表面积和超顺磁性特性而备受关注。由多糖组成的生物聚合物,包括藻酸盐、纤维素、葡萄糖、糊精、壳聚糖和淀粉,可以固定在磁性纳米颗粒上。生物聚合物可以从天然来源获得,如植物、被囊动物、藻类和细菌。从天然来源获得的生物聚合物因其各种特性而受到关注,包括高效官能团、无毒、低成本、可得性和生物相容性。根据“绿色化学”的目标,生物聚合物的应用在减少污染方面是有效的。此外,它们是用于磁性纳米颗粒功能化以产生纳米磁性生物聚合物的优良试剂,可作为多组分反应中可回收且环保的催化剂应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/16c5/9039991/a169526b7d49/d2ra01294d-f1.jpg

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