Liu Shuwen, Qiu Jun, Han Lili, Ma Xueyan, Chen Wenquan
College of Material Science and Engineering, Tongji University, Shanghai 200082, China.
Pan Asia Technical Automotive Center Co., Ltd., Shanghai 201201, China.
Polymers (Basel). 2022 Apr 28;14(9):1795. doi: 10.3390/polym14091795.
Hydrogenated styrene-butadiene-styrene block copolymer (SEBS)/polypropylene (PP) blended thermoplastic elastomer (TPE) is suitable for preparing the automotive interiors because of its excellent elasticity, softness, weather resistance, low odor, low VOC and other environmental-friendly properties. The skin of the automobile instrument panel is an appearance part, which requires excellent friction loss resistance of surface. In this paper, the high-flow SEBS/PP blended thermoplastic elastomer (TPE) suitable for the preparation of injection molding skins for automobile instrument panel was studied. By comparing the Taber abrasion and cross-scratch properties, the effects of SEBS's molecular weight, styrene content in the molecule, molecular structure and types of lubricating agents on the friction loss properties of the material were investigated. The results show that under the same SEBS molecular structure, the higher the molecular weight within a certain range, the better the wear resistance of high-flow SEBS/PP type TPE, but the ultra-high molecular weight exhibits lower wear resistance than high molecular weight; The high-flow SEBS/PP blended TPE prepared by medium styrene content SEBS has better abrasion resistance; TPE prepared by star SEBS is better than linear SEBS; Adding silane-based lubricating agents is beneficial to improve the friction loss resistance of the material, especially combined use of high and low molecular weight silicone.
氢化苯乙烯-丁二烯-苯乙烯嵌段共聚物(SEBS)/聚丙烯(PP)共混热塑性弹性体(TPE)因其优异的弹性、柔软性、耐候性、低气味、低挥发性有机化合物等环保性能,适用于制备汽车内饰件。汽车仪表板表皮是外观件,要求表面具有优异的耐磨耗性能。本文研究了适用于制备汽车仪表板注塑表皮的高流动SEBS/PP共混热塑性弹性体(TPE)。通过对比泰伯磨耗和交叉划痕性能,研究了SEBS的分子量、分子中苯乙烯含量、分子结构以及润滑剂种类对材料耐磨耗性能的影响。结果表明:在相同SEBS分子结构下,一定范围内分子量越高,高流动SEBS/PP型TPE的耐磨性越好,但超高分子量的耐磨性低于高分子量的;中等苯乙烯含量SEBS制备的高流动SEBS/PP共混TPE具有较好的耐磨耗性;星形SEBS制备的TPE优于线性SEBS;添加硅烷类润滑剂有利于提高材料的耐磨耗性能,尤其是高低分子量硅油复配使用时。