多环氮杂叶立德与诺科尔的 1,3-偶极环加成反应：制备二苯并[g,l]嗪稠合衍生物。
1,3-Dipolar cycloaddition of polycyclic azomethine ylide to norcorroles: towards dibenzoullazine-fused derivatives.
机构信息
Key Laboratory of Theoretical Organic Chemistry and Functional Molecules, Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology Xiangtan, Hunan 411201, China.
Department of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50 383 Wrocław, Poland.
出版信息
Chem Commun (Camb). 2022 Jun 1;58(45):6510-6513. doi: 10.1039/d2cc02071h.
A 1,3-cycloaddition reaction of 2-(-butyl)-8-isoquinolino[4,3,2-]phenanthridin-9-ium chloride to Ni norcorrole in the presence of base is shown to produce a family of chiral derivatives of polycyclic system(s) fused with pyrrole subunit(s) of the macrocycle. Dehydrogenation of the cycloaddition products gave rise to dibenzoullazine -fused antiaromatic porphyrinoids.
在碱的存在下，2-(-丁基)-8-异喹啉并[4,3,2-]菲啶-9-翁氯化物与 Ni 诺科尔的 1,3-环加成反应生成了一系列具有稠合的多环系统和吡咯单元的手性衍生物。环加成产物的脱氢反应生成了二苯并[g,h]氮杂菲并稠合的反芳香卟啉。
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