Bian Ye, Niu Zhuolun, Wang Shijie, Pan Yue, Zhang Li, Chen Chun
School of Energy and Environment, Southeast University, Nanjing 210096, China.
Department of Mechanical and Automation Engineering, The Chinese University of Hong Kong, Shatin, N.T. 999077, Hong Kong SAR, China.
ACS Appl Mater Interfaces. 2022 May 17. doi: 10.1021/acsami.2c04970.
Particulate matter poses a serious threat to human health. In particular, exposure to submicron particles can result in more severe health effects as they can deposit more deeply into human tissues. Metal-organic framework (MOF)-based nanofiber filters are regarded as promising candidates for efficient particle control. In this study, ZIF-8@PAN nanofiber filters that were developed via an in situ growth strategy were selected for the filtration of submicron particles. The addition of ZIF-8 more effectively enhanced the filtration of particles with smaller sizes. For the most penetrating particle size of around 0.3 μm, the MOF-based nanofiber filter exhibited an 8.9% increase in filtration efficiency compared with that of the pure nanofiber filter. Meanwhile, for particles with large aerodynamic diameters (in the range of 0.7-1 μm, for example), the role of ZIF-8 was negligible. This work provides important insights into the filtration performance of MOF-based nanofiber filters in capturing submicron particles and may aid in designing nanofiber filters for efficient control of particles.
颗粒物对人类健康构成严重威胁。特别是,接触亚微米颗粒会导致更严重的健康影响,因为它们可以更深入地沉积在人体组织中。基于金属有机框架(MOF)的纳米纤维过滤器被认为是有效控制颗粒的有前途的候选材料。在本研究中,选择通过原位生长策略开发的ZIF-8@PAN纳米纤维过滤器用于过滤亚微米颗粒。ZIF-8的添加更有效地增强了对较小尺寸颗粒的过滤。对于最易穿透粒径约为0.3μm的颗粒,基于MOF的纳米纤维过滤器的过滤效率比纯纳米纤维过滤器提高了8.9%。同时,对于空气动力学直径较大的颗粒(例如在0.7-1μm范围内),ZIF-8的作用可以忽略不计。这项工作为基于MOF的纳米纤维过滤器在捕获亚微米颗粒方面的过滤性能提供了重要见解,并可能有助于设计用于有效控制颗粒的纳米纤维过滤器。