University of Coimbra, CIEPQPF , Department of Chemical Engineering , PT, Coimbra, Portugal.
RAIZ - Forest and Paper Research Institute, Quinta de S. Francisco, Apartado 15, PT, Portugal.
Adv Exp Med Biol. 2022;1357:129-151. doi: 10.1007/978-3-030-88071-2_6.
Nanocelluloses are a very promising material that has been widely explored for the most diverse applications. The pursuit for sustainable and environmentally friendly materials is in line with the nature of nanocelluloses and therefore they have emerged as the perfect candidate for plastics substitution, food additive, rheology controller, 3D printing of diverse structures, among many other possibilities. This derives from their interesting characteristics, such as reduced size and high specific surface area, high tensile strength, crystallinity and transparency, and from the fact that, such as cellulose, they are obtained from renewable sources, with relative ease for functionalization in order to obtain desired specificities. Thus, the industry is trying to react and effectively respond to the exponential growth of published research in the last years, and therefore new facilities (not only lab and pilot plants but already industrial sites) have been producing nanocelluloses. This new fibrous materials can be obtained from different raw-materials by different methodologies, leading to different types of nanocelluloses with, obviously, different characteristics. Nonetheless, technical and economical constraints have been addressed, such as the high energy demand or the clogging of homogenizers/microfluidizers.This chapter intends to present a review addressing the main features related to the production, characterization and market of nanocelluloses and providing additional information regarding the vast literature published in these domains.
纳米纤维素是一种非常有前途的材料,已经被广泛探索用于最多样化的应用。追求可持续和环保的材料与纳米纤维素的性质一致,因此它们已成为塑料替代品、食品添加剂、流变学控制器、各种结构的 3D 打印等的理想候选材料。这源于它们的有趣特性,如尺寸减小和比表面积高、拉伸强度高、结晶度和透明度高,以及与纤维素一样,它们是从可再生资源中获得的,相对容易进行功能化以获得所需的特异性。因此,工业界正在努力应对并有效响应近年来发表的研究呈指数级增长的情况,因此新的设施(不仅是实验室和中试工厂,还有工业现场)已经开始生产纳米纤维素。这种新型纤维材料可以通过不同的方法从不同的原料中获得,导致具有不同特性的不同类型的纳米纤维素。尽管如此,技术和经济方面的限制已经得到了解决,例如高能耗或均化器/微流化器的堵塞。本章旨在综述与纳米纤维素的生产、表征和市场相关的主要特征,并提供有关这些领域发表的大量文献的更多信息。