键合相高效液相色谱法中大型多环芳烃的保留行为
Retention behavior of large polycyclic aromatics in bonded-phase high-performance liquid chromatography.
作者信息
Fetzer J C, Biggs W R
出版信息
J Chromatogr. 1987 Jan 16;386:87-101. doi: 10.1016/s0021-9673(01)94587-x.
PMID:3558618
Abstract
The retention behavior of 31 large polycyclic aromatic hydrocarbons was studied on polymeric octadecyl-bonded columns, with methanol-dichloromethane mobile phases. Three types of elution behavior were observed, dependent on the degree of intramolecular strain in the polycyclic aromatic hydrocarbons.
摘要
研究了31种大型多环芳烃在聚合物十八烷基键合柱上，以甲醇 - 二氯甲烷为流动相时的保留行为。观察到三种洗脱行为类型，这取决于多环芳烃分子内应变的程度。
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