Nakamura Issei, Wang Zhen-Gang
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, People's Republic of China.
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States.
ACS Macro Lett. 2014 Aug 19;3(8):708-711. doi: 10.1021/mz500301z. Epub 2014 Jul 10.
We provide a perspective on the thermodynamics of salt-doped block copolymer electrolytes consisting of ion-conducting and inert blocks, taking poly(ethylene oxide)--polystyrene and lithium salts as an example. We focus on the origin for enhanced immiscibility between the constituent blocks upon addition of lithium salts and discuss issues from selected experiments and from our recent self-consistent field study.
我们以聚环氧乙烷-聚苯乙烯和锂盐为例，对由离子导电嵌段和惰性嵌段组成的盐掺杂嵌段共聚物电解质的热力学进行了探讨。我们关注添加锂盐后组成嵌段之间不相容性增强的根源，并从选定的实验以及我们最近的自洽场研究来讨论相关问题。
