Chaskis Spyridon, Stachouli Eva, Gavalas Evangelos, Bouzouni Marianthi, Papaefthymiou Spyros
Laboratory of Physical Metallurgy, Division of Metallurgy and Materials, School of Mining and Metallurgical Engineering, National Technical University of Athens, 9, Heroon Polytechniou Street, 15780 Athens, Greece.
Technology, Marketing and R&D Department of HALCOR, Copper Tubes and Alloys Extrusion Division, ELVALHALCOR S.A., 62nd km Athens-Lamia National Road, 32011 Oinofyta, Greece.
Materials (Basel). 2022 Apr 27;15(9):3169. doi: 10.3390/ma15093169.
In the current work, a novel complex concentrated aluminum alloy is designed and studied. In order to investigate the unknown region of the multicomponent phase diagrams, thermo-physical parameters and the CALPHAD method were used to understand the phase formation of the AlMgZnCuSi at.% (Al.Mg.Zn.Cu.Siwt.%) alloy with a low-density of 2.63 g/cm. The CALPHAD methodology showed good agreement with both the investigated microstructure and the thermodynamic parameters. The designed alloy was manufactured using an induction furnace and pour mold casting process. This study avoids the use of expensive, dangerous or scarce alloying elements and focuses instead on the utilization of widely available relatively cheaper elements. The microstructural evolution as a function of the heat-treatment was studied by means of different microstructural characterization techniques. The hardness, compressive strength and electrical conductivity of the as-cast and heat-treated alloy at room temperature were studied and correlated with the previously characterized microstructure. The alloy is characterized by a multiphase microstructure with major α-Al matrix reinforced with various secondary phases. In terms of mechanical properties, the developed alloy exhibited a high hardness value of 249 Vickers and compressive strength of 588 MPa. The present work provides a valuable insight for researchers, who aim to design and produce industry-like Aluminum based complex concentrated alloys (CCAs).
在当前工作中,设计并研究了一种新型复合浓缩铝合金。为了研究多元相图的未知区域,利用热物理参数和CALPHAD方法来了解AlMgZnCuSi原子百分比(Al.Mg.Zn.Cu.Si重量百分比)、密度为2.63 g/cm³的合金的相形成情况。CALPHAD方法与所研究的微观结构和热力学参数均显示出良好的一致性。所设计的合金采用感应炉和浇铸成型工艺制造。本研究避免使用昂贵、危险或稀缺的合金元素,而是专注于利用广泛可得的相对便宜的元素。通过不同的微观结构表征技术研究了作为热处理函数的微观结构演变。研究了铸态和热处理合金在室温下的硬度、抗压强度和电导率,并将其与先前表征的微观结构相关联。该合金的特征是具有多相微观结构,主要的α-Al基体由各种第二相强化。在力学性能方面,所开发的合金表现出249维氏硬度值和588 MPa的抗压强度。本工作为旨在设计和生产类似工业用铝基复合浓缩合金(CCA)的研究人员提供了有价值的见解。