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多维系统与多个热库耦合的强化第二定律。

Strengthened second law for multi-dimensional systems coupled to multiple thermodynamic reservoirs.

机构信息

Santa Fe Institute, Santa Fe, NM, USA.

Complexity Science Hub, Vienna, Arizona State University, Tempe, AZ, USA.

出版信息

Philos Trans A Math Phys Eng Sci. 2022 Jul 11;380(2227):20200428. doi: 10.1098/rsta.2020.0428. Epub 2022 May 23.

Abstract

The second law of thermodynamics can be formulated as a restriction on the evolution of the entropy of any system undergoing Markovian dynamics. Here I show that this form of the second law is strengthened for multi-dimensional, complex systems, coupled to multiple thermodynamic reservoirs, if we have a set of constraints restricting how the dynamics of each coordinate can depend on the other coordinates. As an example, this strengthened second law (SSL) applies to complex systems composed of multiple physically separated, co-evolving subsystems, each identified as a coordinate of the overall system. In this example, the constraints concern how the dynamics of some subsystems are allowed to depend on the states of the other subsystems. Importantly, the SSL applies to such complex systems even if some of its subsystems can change state simultaneously, which is prohibited in a multipartite process. The SSL also strengthens previously derived bounds on how much work can be extracted from a system using feedback control, if the system is multi-dimensional. Importantly, the SSL does not require local detailed balance. So it potentially applies to complex systems ranging from interacting economic agents to co-evolving biological species. This article is part of the theme issue 'Emergent phenomena in complex physical and socio-technical systems: from cells to societies'.

摘要

热力学第二定律可以表述为对任何经历马尔可夫动力学的系统的熵演化的限制。在这里,我表明,如果我们有一组约束条件限制每个坐标的动力学如何依赖于其他坐标,那么这种形式的第二定律对于多维复杂系统与多个热力学储库耦合时会得到加强。例如,这种强化的第二定律(SSL)适用于由多个物理上分离、共同演化的子系统组成的复杂系统,每个子系统都被确定为整个系统的一个坐标。在这个例子中,约束条件涉及某些子系统的动力学如何允许依赖于其他子系统的状态。重要的是,即使某些子系统可以同时改变状态(这在多部分过程中是禁止的),SSL 也适用于这样的复杂系统。SSL 还加强了以前关于使用反馈控制从系统中提取多少功的限制,如果系统是多维的。重要的是,SSL 不需要局部详细平衡。因此,它可能适用于从相互作用的经济主体到共同进化的生物物种等复杂系统。本文是主题为“复杂物理和社会技术系统中的涌现现象:从细胞到社会”的一部分。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/932d/9125225/72a4c6923f24/rsta20200428f01.jpg

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