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再生稻壳增强PVC复合型材用于外墙覆层的效用

The Utility of Recycled Rice Husk-Reinforced PVC Composite Profiles for Façade Cladding.

作者信息

Sudoł Ewa, Kozikowska Ewelina, Choińska Emilia

机构信息

Construction Materials Engineering Department, Instytut Techniki Budowlanej, 00-611 Warsaw, Poland.

Faculty of Materials Science and Engineering, Warsaw University of Technology, 02-507 Warsaw, Poland.

出版信息

Materials (Basel). 2022 May 10;15(10):3418. doi: 10.3390/ma15103418.

Abstract

The production process of construction profiles from natural fibre-reinforced polymer composites, as well as their assembly, generates considerable amounts of waste. The study analysed the possibility of utilising the said waste to produce profiles with the same intended use as products made from the primary material. The analysis involved the recycling of rice husk-reinforced PVC profiles. As a result of the applied post-processing, a composite of higher homogeneity and better filler dispersion than the product made of primary material was obtained. A slight improvement in thermal properties was observed. From the DSC test, Tg values of 78 °C and nearly 80 °C were obtained, while from the TGA test, mass loss values of 0.6% and 0.4% and the decomposition temperatures of 211 °C and 217 °C were noted for profiles of primary and secondary material, respectively. A softening temperature of 75 °C was obtained for primary material profiles, while nearly 77 °C was obtained for secondary. The more favourable mechanical properties of recycled profiles were also maintained. The higher value of flexural strength, flexural modulus, impact strength and hardness by 31%, 24%, 48% and 40% were obtained, respectively. After hydrothermal cycling, the same properties were higher for secondary material profiles by 35%, 20%, 68%, and 67%, respectively. The recorded level of performance properties of recycled products, better than those of primary material standard construction products', allows us to conclude that profiles made of waste are useful for façade claddings.

摘要

天然纤维增强聚合物复合材料建筑型材的生产过程及其组装会产生大量废物。该研究分析了利用上述废物生产与由主要材料制成的产品具有相同预期用途的型材的可能性。分析涉及稻壳增强PVC型材的回收利用。经过后处理,得到了一种比由主要材料制成的产品具有更高均匀性和更好填料分散性的复合材料。观察到热性能有轻微改善。从DSC测试中,获得了78℃和近80℃的玻璃化转变温度(Tg)值,而从TGA测试中,主要材料和二次材料型材的质量损失值分别为0.6%和0.4%,分解温度分别为211℃和217℃。主要材料型材的软化温度为75℃,而二次材料型材的软化温度接近77℃。回收型材更有利的机械性能也得以保持。回收型材的弯曲强度、弯曲模量、冲击强度和硬度值分别比主要材料型材高出31%、24%、48%和40%。经过水热循环后,二次材料型材的相同性能分别比主要材料型材高出35%、20%、68%和67%。回收产品记录的性能水平优于主要材料标准建筑产品,这使我们得出结论,由废物制成的型材可用于外墙覆层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e56/9145044/ffb751793bc4/materials-15-03418-g001.jpg

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