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埃洛石粘土纳米复合材料表面性质的原子力显微镜表征:当前技术水平与展望

AFM Characterization of Halloysite Clay Nanocomposites' Superficial Properties: Current State-of-the-Art and Perspectives.

作者信息

Cascione Mariafrancesca, De Matteis Valeria, Persano Francesca, Leporatti Stefano

机构信息

Department of Mathematics & Physics "Ennio De Giorgi", University of Salento, Via Arnesano, 73100 Lecce, Italy.

CNR Nanotec-Institute of Nanotechnology, Via Monteroni, 73100 Lecce, Italy.

出版信息

Materials (Basel). 2022 May 10;15(10):3441. doi: 10.3390/ma15103441.

DOI:10.3390/ma15103441
PMID:35629468
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9146693/
Abstract

Natural halloysite clay nanotubes (HNTs) are versatile inorganic reinforcing materials for creating hybrid composites. Upon doping HNTs with polymers, coating, or loading them with bioactive molecules, the production of novel nanocomposites is possible, having specific features for several applications. To investigate HNTs composites nanostructures, AFM is a very powerful tool since it allows for performing nano-topographic and morpho-mechanical measurements in any environment (air or liquid) without treatment of samples, like electron microscopes require. In this review, we aimed to provide an overview of recent AFM investigations of HNTs and HNT nanocomposites for unveiling hidden characteristics inside them envisaging future perspectives for AFM as a smart device in nanomaterials characterization.

摘要

天然埃洛石粘土纳米管(HNTs)是用于制备杂化复合材料的多功能无机增强材料。通过用聚合物对HNTs进行掺杂、包覆或负载生物活性分子,可以制备出具有特定特性、适用于多种应用的新型纳米复合材料。为了研究HNTs复合材料的纳米结构,原子力显微镜(AFM)是一种非常强大的工具,因为它可以在任何环境(空气或液体)中对样品进行纳米形貌和形态力学测量,而无需像电子显微镜那样对样品进行处理。在这篇综述中,我们旨在概述AFM对HNTs和HNT纳米复合材料的最新研究,以揭示其内部隐藏的特性,并展望AFM作为纳米材料表征智能设备的未来前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c9/9146693/067da13cb210/materials-15-03441-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c9/9146693/03cf91863b2c/materials-15-03441-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c9/9146693/bb7548ec0f19/materials-15-03441-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c9/9146693/24a76dbf32f9/materials-15-03441-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c9/9146693/067da13cb210/materials-15-03441-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c9/9146693/03cf91863b2c/materials-15-03441-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c9/9146693/bb7548ec0f19/materials-15-03441-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c9/9146693/24a76dbf32f9/materials-15-03441-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c9/9146693/067da13cb210/materials-15-03441-g004.jpg

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Langmuir. 2021 Oct 12;37(40):11869-11879. doi: 10.1021/acs.langmuir.1c01949. Epub 2021 Oct 4.
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Recent advances in the design of inorganic and nano-clay particles for the treatment of brain disorders.
用于治疗脑部疾病的无机和纳米粘土颗粒设计的最新进展。
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Past, Present and Future Perspectives on Halloysite Clay Minerals.埃洛石黏土矿物的过去、现在和未来展望。
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Facile Fabrication of Natural Polyelectrolyte-Nanoclay Composites: Halloysite Nanotubes, Nucleotides and DNA Study.天然高分子电解质-纳米粘土复合材料的简易制备:埃洛石纳米管、核苷酸和 DNA 的研究。
Molecules. 2020 Aug 4;25(15):3557. doi: 10.3390/molecules25153557.
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