Itagaki Hideyuki, Sano Takumi, Okabe Toshihiko, Sano Shota, Ebihara Hirohide, Tomono Fumika, Dohra Hideo
Department of Chemistry, Graduate School of Science and Technology, ‡Department of Chemistry, School of Education, and §Research Institute of Green Science and Technology, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529, Japan.
Department of Chemistry, Graduate School of Science and Technology, Department of Chemistry, School of Education, and §Research Institute of Green Science and Technology, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529, Japan.
ACS Macro Lett. 2017 Oct 17;6(10):1099-1103. doi: 10.1021/acsmacrolett.7b00661. Epub 2017 Sep 20.
Syndiotactic polystyrene (SPS) has a unique crystalline phase, named ε, that has a tubular cavity inside. We connected these cavities by optimizing the solvent used to process the films and to polymerize aniline within these channeling cavities only by immersing the films in degassed hydrochloric acid solutions of ammonium persulfate. We succeeded in fixing pentameric to octameric oligoaniline in the cavities of the SPS ε crystalline phase. This is a new and sophisticated preparation method of polymer composites between SPS and linear oligomers/polymers within its long-connected tubular cavities.
间规聚苯乙烯（SPS）具有一种独特的晶相，称为ε相，其内部有管状空腔。我们通过优化用于处理薄膜的溶剂，并仅通过将薄膜浸入过硫酸铵的脱气盐酸溶液中，使苯胺在这些通道状空腔内聚合，从而连通了这些空腔。我们成功地将五聚体至八聚体的低聚苯胺固定在SPS ε晶相的空腔中。这是一种在SPS及其长连通管状空腔内的线性低聚物/聚合物之间制备聚合物复合材料的新型复杂制备方法。
