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用于高效室温一氧化碳气体传感的聚苯胺/(氧化钽-氧化锡)混合纳米复合材料

Polyaniline/(TaO-SnO) hybrid nanocomposite for efficient room temperature CO gas sensing.

作者信息

Aranthady Chethana, Shanbhag Ganapati V, Sundaram Nalini G

机构信息

Materials Science and Catalysis Division, Poornaprajna Institute of Scientific Research Devanahalli-562164 Bengaluru India

Graduate Studies, Manipal Academy of Higher Education Manipal-576104 Karnataka India.

出版信息

RSC Adv. 2022 May 25;12(25):15759-15766. doi: 10.1039/d2ra00602b. eCollection 2022 May 23.

Abstract

Development of efficient CO sensors that can detect low concentration CO at room temperature is of prime importance. Herein, we present a TaO-SnO-PANI hybrid composite for the efficient sensing of CO at room temperature and at very low concentrations. The material was synthesized by the oxidative polymerization method. The structural and morphological characteristics of the nanostructured (TaO-SnO)-PANI hybrid composite were examined using p-XRD and FESEM techniques. The oxygen vacancies in the material were confirmed by XPS analysis. The hybrid material exhibited superior CO sensing performance with high sensitivity, low operating temperature, and fast response and recovery time compared to the individual counterparts. The enhanced sensing ability of the hybrid material is accredited to the synergistic properties such as conductivity of PANI, improved oxygen vacancies and the heterostructure formed between the PANI and the (TaO-SnO) composite. These remarkable features make TaSn : PANI a potential sensor at room temperature for sensing of low concentration CO.

摘要

开发能够在室温下检测低浓度一氧化碳的高效一氧化碳传感器至关重要。在此,我们展示了一种用于在室温和极低浓度下高效检测一氧化碳的TaO-SnO-PANI混合复合材料。该材料通过氧化聚合法合成。使用p-XRD和FESEM技术研究了纳米结构的(TaO-SnO)-PANI混合复合材料的结构和形态特征。通过XPS分析证实了材料中的氧空位。与单独的对应物相比,该混合材料表现出优异的一氧化碳传感性能,具有高灵敏度、低工作温度以及快速的响应和恢复时间。混合材料增强的传感能力归因于诸如PANI的导电性、改善的氧空位以及PANI与(TaO-SnO)复合材料之间形成的异质结构等协同特性。这些显著特性使TaSn : PANI成为室温下用于检测低浓度一氧化碳的潜在传感器。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/219d/9132034/770d20fda7de/d2ra00602b-f1.jpg

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