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[青海湖沉积物中重金属的分布及潜在生态风险评估]

[Distribution and Potential Ecological Risk Assessment of Heavy Metals in Sediments of Lake Qinghai].

作者信息

Zhang Ya-Ran, Che Fei-Fei, Fu Zheng-Hui, Xu Ye, Li Wei

机构信息

College of Environment Sciences and Engineering, North China Electric Power University, Beijing 102206, China.

National Engineering Laboratory for Lake Pollution Control and Ecological Restoration, State Environment Protection Key Laboratory for Lake Pollution Control, Chinese Research Academy of Environmental Sciences, Beijing 100012, China.

出版信息

Huan Jing Ke Xue. 2022 Jun 8;43(6):3037-3047. doi: 10.13227/j.hjkx.202108201.

Abstract

Lake Qinghai is the largest closed saltwater lake in China. In recent years, because of the rapid development of industry, agriculture, and tourism, the lake has been increasingly affected by human activities, which has attracted the attention of many scholars. In order to understand the distribution of heavy metals in the surface sediments of Lake Qinghai, the contents of Zn, Cu, Pb, Co, Ni, As, Cd, and Cr were investigated, the metal fractions were extracted, and the sources, as well as potential ecological risks, were analyzed. The results showed that:① the (As) (13.21 mg·kg) and (Cd) (0.21 mg·kg) in the surface sediments of Lake Qinghai were 1.13 and 1.53 times higher than the environmental background values, respectively, and the other heavy metal contents were all lower than the environmental background values. There were similar spatial distribution characteristics of analyzed metals except for As, with higher values measured in the northwestern area of the lake and the 151 Terminal. ② Except for Cd, the analyzed heavy metals mainly existed in the form of the residual state; by contrast, Cd mainly existed in the form of the bioavailable state, which has high potential toxicity to aquatic organisms. ③ Combined with the results of the correlation and principal component analysis, the metals including Zn, Cu, Pb, Co, Ni, Cd, and Cr were thought to mainly come from the natural environment, whereas the source of As was related to human activities, such as agricultural production. ④ According to potential risk analyses, the average of the metal potential ecological risk factors was 76.57, which indicated a slight ecological hazard level. However, it should be noted that the potential ecological hazard level and release risk of Cd at each site were higher than those of the other metals, especially in the regions nearing the estuary of Heima River, Lake Gahai, and the sand island, which showed higher levels of enrichment and potential release risk. Therefore, further attention should be paid to the potential impacts of Cd in sediments of these regions on the water environment and ecosystem.

摘要

青海湖是中国最大的封闭性咸水湖。近年来,由于工业、农业和旅游业的快速发展,该湖泊受人类活动的影响日益增大,这引起了众多学者的关注。为了解青海湖表层沉积物中重金属的分布情况,对锌、铜、铅、钴、镍、砷、镉和铬的含量进行了调查,提取了金属形态,并分析了其来源以及潜在生态风险。结果表明:①青海湖表层沉积物中的砷(13.21毫克·千克)和镉(0.21毫克·千克)分别比环境背景值高1.13倍和1.53倍,其他重金属含量均低于环境背景值。除砷外,所分析金属具有相似的空间分布特征,在湖泊西北部地区和151基地测得的值较高。②除镉外,所分析的重金属主要以残渣态存在;相比之下,镉主要以生物可利用态存在,对水生生物具有较高的潜在毒性。③结合相关性和主成分分析结果,锌、铜、铅、钴、镍、镉和铬等金属主要来源于自然环境,而砷的来源与农业生产等人类活动有关。④根据潜在风险分析,金属潜在生态风险因子的平均值为76.57,表明生态危害程度较轻。然而,应当注意的是,各点位镉的潜在生态危害程度和释放风险均高于其他金属,尤其是在靠近黑马河河口、尕海湖和沙岛的区域,其富集程度和潜在释放风险较高。因此,应进一步关注这些区域沉积物中镉对水环境和生态系统的潜在影响。

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