Ghaffari Zahra, Rezvani Hosein, Khalilnezhad Ali, Cortes Farid B, Riazi Masoud
Enhanced Oil Recovery (EOR) Research Centre, IOR/EOR Research Institute, Shiraz University, Shiraz, Iran.
Faculty of Petroleum and Natural Gas Engineering, Sahand University of Technology, Tabriz, Iran.
Sci Rep. 2022 Jun 10;12(1):9628. doi: 10.1038/s41598-022-13035-1.
High water production in oil fields is an area of concern due to economic issues and borehole/wellhead damages. Colloidal gels can be a good alternative to polymers to address this as they can tolerate harsh oil reservoir conditions. A series of bottle tests with different silica and NaCl concentrations were first conducted. The gelation time, cation valence, rheology, and viscosity were investigated to characterize the gels. The applicability of solid gels in porous media was finally inspected in a dual-patterned glass micromodel. Bottle test results showed that increasing NaCl concentration at a constant silica concentration can convert solid gels into two-phase gels and then viscous suspensions. Na replacement with Mg resulted a distinctive behaviour probably due to higher coagulating ability of Mg. Rheology and viscosity results agreed with gelation times: gel with shortest gelation time had the highest viscosity and storage/loss modulus but was not the most elastic one. Water injection into glass micromodel half-saturated with crude oil and solid gel proved that the gel is strong against pressure gradients applied by injected phase which is promising for water conformance controls. The diverted injected phase recorded an oil recovery of 53% which was not feasible without blocking the water zone.
由于经济问题以及井眼/井口损坏,油田的高产水是一个备受关注的领域。胶体凝胶可以作为聚合物的良好替代品来解决这一问题,因为它们能够耐受恶劣的油藏条件。首先进行了一系列不同二氧化硅和氯化钠浓度的瓶试。研究了凝胶时间、阳离子价态、流变学和粘度以表征这些凝胶。最后在双图案玻璃微模型中考察了固体凝胶在多孔介质中的适用性。瓶试结果表明,在二氧化硅浓度恒定的情况下增加氯化钠浓度可使固体凝胶转变为两相凝胶,进而转变为粘性悬浮液。用镁替代钠导致了一种独特的行为,这可能是由于镁具有更高的凝聚能力。流变学和粘度结果与凝胶时间一致:凝胶时间最短的凝胶具有最高的粘度以及储能/损耗模量,但并非弹性最大的凝胶。向原油和固体凝胶半饱和的玻璃微模型中注水证明,该凝胶对于注入相施加的压力梯度具有很强的耐受性,这对于控水是很有前景的。转向注入相的原油采收率达到了53%,如果不封堵水区这是不可行的。