Zaki Shrouk E, Basyooni Mohamed A
Department of Nanotechnology and Advanced Materials, Graduate School of Applied and Natural Science, Selçuk University, Konya, 42030, Turkey.
Theoretical Physics Department, National Research Center, Dokki, Cairo, Egypt.
Sci Rep. 2022 Jun 13;12(1):9759. doi: 10.1038/s41598-022-13898-4.
Ultra-sensitive greenhouse gas sensors for CO, NO, and CH gases based on Fano resonance modes have been observed through periodic and quasi-periodic phononic crystal structures. We introduced a novel composite based on metal/2D transition metal dichalcogenides (TMDs), namely; platinum/platinum disulfide (Pt/PtS) composite materials. Our gas sensors were built based on the periodic and quasi-periodic phononic crystal structures of simple Fibonacci (F(5)) and generalized Fibonacci (FC(7, 1)) quasi-periodic phononic crystal structures. The FC(7, 1) structure represented the highest sensitivity for CO, NO, and CH gases compared to periodic and F(5) phononic crystal structures. Moreover, very sharp Fano resonance modes were observed for the first time in the investigated gas sensor structures, resulting in high Fano resonance frequency, novel sensitivity, quality factor, and figure of merit values for all gases. The FC(7, 1) quasi-periodic structure introduced the best layer sequences for ultra-sensitive phononic crystal greenhouse gas sensors. The highest sensitivity was introduced by FC(7, 1) quasiperiodic structure for the CH with a value of 2.059 (GHz/m.s). Further, the temperature effect on the position of Fano resonance modes introduced by FC(7, 1) quasi-periodic PhC gas sensor towards CH gas has been introduced in detail. The results show the highest sensitivity at 70 °C with a value of 13.3 (GHz/°C). Moreover, the highest Q and FOM recorded towards CH have values of 7809 and 78.1 (m.s) respectively at 100 °C.
通过周期性和准周期性声子晶体结构,观测到了基于法诺共振模式的用于检测一氧化碳、一氧化氮和甲烷气体的超灵敏温室气体传感器。我们引入了一种基于金属/二维过渡金属二硫属化物(TMDs)的新型复合材料,即铂/二硫化铂(Pt/PtS)复合材料。我们的气体传感器基于简单斐波那契(F(5))和广义斐波那契(FC(7, 1))准周期性声子晶体结构的周期性和准周期性声子晶体结构构建。与周期性和F(5)声子晶体结构相比,FC(7, 1)结构对一氧化碳、一氧化氮和甲烷气体表现出最高的灵敏度。此外,在研究的气体传感器结构中首次观测到了非常尖锐的法诺共振模式,这为所有气体带来了高法诺共振频率、新颖的灵敏度、品质因数和优值。FC(7, 1)准周期性结构为超灵敏声子晶体温室气体传感器引入了最佳的层序列。FC(7, 1)准周期性结构对甲烷的灵敏度最高,值为2.059(GHz/m.s)。此外,还详细介绍了FC(7, 1)准周期性声子晶体气体传感器对甲烷气体所引入的法诺共振模式位置的温度影响。结果表明,在70°C时灵敏度最高,值为13.3(GHz/°C)。此外,在100°C时,对甲烷记录到的最高品质因数和优值分别为7809和78.1(m.s)。