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以水果提取物为还原剂微波辅助合成Ag/ZnO纳米粒子及其在具有抗菌和紫外线防护性能的棉织物中的应用。

Microwave-assisted synthesis of Ag/ZnO nanoparticles using fruit extract as the reducing agent and their application in cotton fabrics with antibacterial and UV-protection properties.

作者信息

Porrawatkul Paweena, Pimsen Rungnapa, Kuyyogsuy Arnannit, Teppaya Nongyao, Noypha Amnuay, Chanthai Saksit, Nuengmatcha Prawit

机构信息

Creative Innovation in Science and Technology, Department of Chemistry, Faculty of Science and Technology, Nakhon Si Thammarat Rajabhat University 80280 Thailand

Nanomaterials Chemistry Research Unit, Department of Chemistry, Faculty of Science and Technology, Nakhon Si Thammarat Rajabhat University 80280 Thailand.

出版信息

RSC Adv. 2022 May 18;12(24):15008-15019. doi: 10.1039/d2ra01636b. eCollection 2022 May 17.

Abstract

This is the first time fruit extract has been used as a reducing agent to synthesize Ag/ZnO composites for coating cotton to develop antibacterial activity and UV protection under domestic microwave irradiation. The effects of the molar concentration of silver nitrate solutions, applied power, reaction duration, and pH on the yield of nanoparticles were determined. The treated fabrics were subjected to the investigation of surface morphology and chemical structure using SEM and EDX techniques, respectively. The antibacterial activity of the ZnO NPs and the Ag/ZnO nanocomposite coated on cotton fabric was evaluated against and using the agar well diffusion method. The results revealed good antibacterial activity in the cotton fabric treated with the Ag-doped ZnO composite. The stability of the Ag/ZnO nanocomposite coated fabrics was determined by a wash durability test, the results of which demonstrated that this fabric could retain good antibacterial activity even after 20 wash cycles. The UV-blocking capacity of the treated fabrics was evaluated based on the ultraviolet protection factor (UPF) value determined in the range of 280-400 nm. The UPF value determined for the Ag/ZnO-coated fabric was 69.67 ± 1.53, which indicated an excellent ability to block UV radiation. Collectively, these results demonstrated the Ag/ZnO nanocomposite prepared in the present study as a promising material for preparing textiles with good antibacterial activity and UV protection.

摘要

这是首次将水果提取物用作还原剂,在家庭微波辐射下合成用于涂覆棉织物以产生抗菌活性和紫外线防护功能的Ag/ZnO复合材料。测定了硝酸银溶液的摩尔浓度、施加功率、反应持续时间和pH值对纳米颗粒产率的影响。分别使用扫描电子显微镜(SEM)和能谱仪(EDX)技术对处理后的织物进行表面形态和化学结构研究。采用琼脂扩散法评估涂覆在棉织物上的ZnO纳米颗粒和Ag/ZnO纳米复合材料对[具体菌种1]和[具体菌种2]的抗菌活性。结果表明,用银掺杂的ZnO复合材料处理的棉织物具有良好的抗菌活性。通过洗涤耐久性试验测定了涂覆有Ag/ZnO纳米复合材料的织物的稳定性,结果表明该织物即使经过20次洗涤循环仍能保持良好的抗菌活性。基于在280 - 400 nm范围内测定的紫外线防护系数(UPF)值评估处理后织物的紫外线阻隔能力。测定的涂覆有Ag/ZnO织物的UPF值为69.67±1.53,这表明其具有优异的紫外线辐射阻隔能力。总的来说,这些结果表明本研究中制备的Ag/ZnO纳米复合材料是一种有前景的材料,可用于制备具有良好抗菌活性和紫外线防护功能的纺织品。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9134/9116112/9d141de466dd/d2ra01636b-f1.jpg

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