College of Materials Science and Engineering, Co-Innovation Centre of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China.
Shanghai Formica Decorative Material Co., Ltd., Shanghai 201706, China.
Waste Manag. 2022 Jul 15;149:96-104. doi: 10.1016/j.wasman.2022.06.012. Epub 2022 Jun 18.
Plastic pollution caused by non-degradable petrochemical-based plastics has become a serious environmental problem in China, and the reasonable management of industrial waste and renewable resources remains a huge challenge. Here, we report environment-friendly wood-plastic composites (WPCs), prepared from decorative high-pressure laminate (HPL) sanding dust (filler) and waste thermoplastic food pails (matrix), as well as comprehensively evaluate the processability, mechanical and interfacial properties, indoor safety evaluation. The elemental composition and thermal stability of these two residue materials were suitable for the WPC manufacturing process. The content of HPL sanding dust in WPC was fixed at 60 wt%, and the amount of maleic anhydride grafted polypropylene (MAPP) added was 5 wt%-7 wt%, which maximized the utilization of waste resources, and can obtain impact strength as high as 5-6 kJ/m, tensile strength of 35-42 MPa and flexural strength as high as 43-46 MPa. The developed WPCs had low formaldehyde emissions (≤1.53 mg/m) and slightly improved flame retardancy. Finally, their lower cost (5,035 yuan/ton) and higher eco-efficiency (12.81 yuan/kg CO) characteristics allowed them to be compatible with the current sustainable development requirements. This study provides a novel approach for the utilization of industrial waste and recyclable resources for sustainable replacement of wood-based products.
不可降解的基于石油化工的塑料造成的塑料污染已成为中国一个严重的环境问题,而工业废物和可再生资源的合理管理仍然是一个巨大的挑战。在这里,我们报告了一种环保型木塑复合材料(WPC),它由装饰性高压层压板(HPL)砂光粉尘(填料)和废弃热塑性食品桶(基质)制备,并全面评估了其加工性能、机械和界面性能、室内安全评估。这两种残余材料的元素组成和热稳定性适合 WPC 的制造工艺。WPC 中 HPL 砂光粉尘的含量固定在 60wt%,添加的马来酸酐接枝聚丙烯(MAPP)的量为 5wt%-7wt%,最大限度地利用了废物资源,可获得高达 5-6kJ/m 的冲击强度、35-42MPa 的拉伸强度和高达 43-46MPa 的弯曲强度。开发的 WPC 具有较低的甲醛排放量(≤1.53mg/m)和略有改善的阻燃性。最后,它们较低的成本(5035 元/吨)和较高的生态效率(12.81 元/kg CO)特性使其能够符合当前的可持续发展要求。本研究为利用工业废物和可再生资源为可持续替代木质产品提供了一种新方法。