Leroy César, Mittelette Sébastien, Félix Gautier, Fabregue Nicolas, Špačková Jessica, Gaveau Philippe, Métro Thomas-Xavier, Laurencin Danielle
ICGM, Univ Montpellier, CNRS, ENSCM Montpellier France
IBMM, Univ Montpellier, CNRS, ENSCM Montpellier France.
Chem Sci. 2022 May 6;13(21):6328-6334. doi: 10.1039/d2sc01496c. eCollection 2022 Jun 1.
We present a new approach for following reactions taking place in mechanochemistry, relying on the analysis of the evolution of the sound during milling. We show that differences in sound can be directly correlated to (physico)chemical changes in the reactor, making this technique highly attractive and complementary to others for monitoring mechanochemical reactions. Most notably, it can provide unique information on the actual movements of the beads within the milling jars, which opens new avenues for helping rationalize mechanochemical processes.
我们提出了一种用于跟踪机械化学中发生的反应的新方法,该方法依赖于对研磨过程中声音演变的分析。我们表明,声音的差异可以直接与反应器中的(物理)化学变化相关联,这使得该技术极具吸引力,并且是监测机械化学反应的其他技术的补充。最值得注意的是,它可以提供关于研磨罐内珠子实际运动的独特信息,这为帮助合理化机械化学过程开辟了新途径。