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微米和纳米氧化锌/低密度聚乙烯复合材料的电导率特性研究

Study of the Electrical Conductivity Characteristics of Micro and Nano-ZnO/LDPE Composites.

作者信息

Yu Guang, Cheng Yujia, Duan Zhuohua

机构信息

Mechanical and Electrical Engineering Institute, University of Electronic Science and Technology of China, Zhongshan Institute, Zhongshan 528400, China.

出版信息

Molecules. 2022 Jun 8;27(12):3674. doi: 10.3390/molecules27123674.

DOI:10.3390/molecules27123674
PMID:35744800
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9230541/
Abstract

Polyethylene, a thermoplastic resin made by ethylene polymerization, is widely used in electrical insulation. In this study, low-density polyethylene (LDPE) is used as a matrix with micro- and nano-ZnO particles as a filler to produce different proportions of micro- and nano-ZnO composites by melt blending. These samples are characterized by Polarized Light Microscopy (PLM) and FTIR tests, with their conductance measured under different field strengths. The current density vs. electric field strength (J-E) curve of micro- and nano-ZnO composites under different field strengths are measured and analyzed. The J-E curves of different composites at different temperatures are measured to explore conductance with temperature. The results of these tests showed that nano-ZnO composites successfully suppressed conductivity at elevated temperatures and electric field strengths, while micro-ZnO composites increased the conductivity relative to pure LDPE.

摘要

聚乙烯是一种由乙烯聚合而成的热塑性树脂,广泛应用于电气绝缘领域。在本研究中,低密度聚乙烯(LDPE)被用作基体,微米和纳米氧化锌颗粒作为填料,通过熔融共混制备不同比例的微米和纳米氧化锌复合材料。这些样品通过偏光显微镜(PLM)和傅里叶变换红外光谱(FTIR)测试进行表征,并在不同场强下测量其电导率。测量并分析了不同场强下微米和纳米氧化锌复合材料的电流密度与电场强度(J-E)曲线。测量了不同复合材料在不同温度下的J-E曲线,以探究电导率与温度的关系。这些测试结果表明,纳米氧化锌复合材料在高温和高场强下成功抑制了电导率,而微米氧化锌复合材料相对于纯LDPE提高了电导率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/45b15260080d/molecules-27-03674-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/249f030783f9/molecules-27-03674-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/344e7b1ea78a/molecules-27-03674-g002a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/535506bb9586/molecules-27-03674-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/3d028c3db059/molecules-27-03674-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/1de69a78a616/molecules-27-03674-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/92e196bf4b25/molecules-27-03674-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/298673425297/molecules-27-03674-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/8caf936d91f2/molecules-27-03674-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/ed1c27e4030b/molecules-27-03674-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/e7279dd48aa7/molecules-27-03674-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/45b15260080d/molecules-27-03674-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/249f030783f9/molecules-27-03674-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/344e7b1ea78a/molecules-27-03674-g002a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/535506bb9586/molecules-27-03674-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/3d028c3db059/molecules-27-03674-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/1de69a78a616/molecules-27-03674-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/92e196bf4b25/molecules-27-03674-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/298673425297/molecules-27-03674-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/8caf936d91f2/molecules-27-03674-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/ed1c27e4030b/molecules-27-03674-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/e7279dd48aa7/molecules-27-03674-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0aa/9230541/45b15260080d/molecules-27-03674-g011.jpg

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本文引用的文献

1
The Research of Crystalline Morphology and Breakdown Characteristics of Polymer/Micro-Nano-Composites.聚合物/微纳复合材料的结晶形态与击穿特性研究
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Preparation and Characterization of Epoxy/Alumina Nanocomposites.环氧/氧化铝纳米复合材料的制备与表征
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Preparation of a new high-efficiency resin deodorant from coal gasification fine slag and its application in the removal of volatile organic compounds in polypropylene composites.
以煤气化细渣制备新型高效树脂除臭剂及其在聚丙烯复合材料中挥发性有机化合物去除中的应用
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Materials (Basel). 2019 Mar 5;12(5):761. doi: 10.3390/ma12050761.
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The Synergistic Effects of the Micro and Nano Particles in Micro-nano Composites on Enhancing the Resistance to Electrical Tree Degradation.微纳米复合材料中微纳米颗粒的协同效应对提高抗电树枝化降解的作用。
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