Elsby Matthew R, Baker R Tom
Department of Chemistry and Biomolecular Sciences and Centre for Catalysis Research and Innovation, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada.
Chem Soc Rev. 2020 Dec 21;49(24):8933-8987. doi: 10.1039/d0cs00509f. Epub 2020 Nov 9.
The use of metal-ligand cooperation (MLC) by transition metal bifunctional catalysts has emerged at the forefront of homogeneous catalysis science. Specially designed ligands can serve a Lewis base or Lewis acid function, as an aromatization/dearomatization shuttle, or as an electron reservoir with reversible redox activity. This review encapsulates advances that have been made in this field over the last ten years, focusing exclusively on first-row transition metals, and highlighting significant contributions to mechanistic understanding.
过渡金属双功能催化剂对金属-配体协同作用（MLC）的应用已成为均相催化科学的前沿领域。经过特殊设计的配体可以起到路易斯碱或路易斯酸的作用，作为芳构化/去芳构化穿梭体，或作为具有可逆氧化还原活性的电子储存库。本综述总结了过去十年该领域取得的进展，特别关注第一行过渡金属，并强调了对机理理解的重大贡献。
