Otero-Martínez Clara, Imran Muhammad, Schrenker Nadine J, Ye Junzhi, Ji Kangyu, Rao Akshay, Stranks Samuel D, Hoye Robert L Z, Bals Sara, Manna Liberato, Pérez-Juste Jorge, Polavarapu Lakshminarayana
Department of Physical Chemistry, CINBIO, Universidade de Vigo, Materials Chemistry and Physics Group, Campus Universitario As Lagoas, Marcosende, 36310, Vigo, Spain.
Department of Physical Chemistry, CINBIO, Universidade de Vigo, Campus Universitario As Lagoas, Marcosende, 36310, Vigo, Spain.
Angew Chem Int Ed Engl. 2022 Aug 22;61(34):e202205617. doi: 10.1002/anie.202205617. Epub 2022 Jul 13.
We report here fast A-site cation cross-exchange between APbX perovskite nanocrystals (NCs) made of different A-cations (Cs (cesium), FA (formamidinium), and MA (methylammonium)) at room temperature. Surprisingly, the A-cation cross-exchange proceeds as fast as the halide (X=Cl, Br, or I) exchange with the help of free A-oleate complexes present in the freshly prepared colloidal perovskite NC solutions. This enabled the preparation of double (MACs, MAFA, CsFA)- and triple (MACsFA)-cation perovskite NCs with an optical band gap that is finely tunable by their A-site composition. The optical spectroscopy together with structural analysis using XRD and atomically resolved high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) and integrated differential phase contrast (iDPC) STEM indicates the homogeneous distribution of different cations in the mixed perovskite NC lattice. Unlike halide ions, the A-cations do not phase-segregate under light illumination.
我们在此报告,由不同A阳离子(铯(Cs)、甲脒鎓(FA)和甲铵(MA))制成的APbX钙钛矿纳米晶体(NCs)在室温下能快速进行A位阳离子的交叉交换。令人惊讶的是,在新制备的胶体钙钛矿NC溶液中存在的游离油酸A络合物的帮助下,A阳离子的交叉交换与卤化物(X = Cl、Br或I)交换一样快。这使得能够制备具有通过其A位组成可精细调节的光学带隙的双阳离子(MACs、MAFA、CsFA)和三阳离子(MACsFA)钙钛矿NCs。光谱学以及使用XRD和原子分辨高角度环形暗场扫描透射电子显微镜(HAADF-STEM)和积分差分相衬(iDPC)STEM进行的结构分析表明,不同阳离子在混合钙钛矿NC晶格中均匀分布。与卤离子不同,A阳离子在光照下不会发生相分离。