Suppr超能文献

打破钙钛矿胶体的“红色壁垒”:高荧光效率的甲脒碘化铅和甲脒铯碘化铅纳米晶。

Dismantling the "Red Wall" of Colloidal Perovskites: Highly Luminescent Formamidinium and Formamidinium-Cesium Lead Iodide Nanocrystals.

机构信息

Dipartimento di Scienza e Alta Tecnologia and To.Sca.Lab, Università dell'Insubria , Via Valleggio 11, I-22100 Como, Italy.

Istituto di Crystallografia and To.Sca.Lab, Consiglio Nazionale delle Ricerche , Valleggio 11, I-22100 Como, Italy.

出版信息

ACS Nano. 2017 Mar 28;11(3):3119-3134. doi: 10.1021/acsnano.7b00116. Epub 2017 Mar 3.

Abstract

Colloidal nanocrystals (NCs) of APbX-type lead halide perovskites [A = Cs, CHNH (methylammonium or MA) or CH(NH) (formamidinium or FA); X = Cl, Br, I] have recently emerged as highly versatile photonic sources for applications ranging from simple photoluminescence down-conversion (e.g., for display backlighting) to light-emitting diodes. From the perspective of spectral coverage, a formidable challenge facing the use of these materials is how to obtain stable emissions in the red and infrared spectral regions covered by the iodide-based compositions. So far, red-emissive CsPbI NCs have been shown to suffer from a delayed phase transformation into a nonluminescent, wide-band-gap 1D polymorph, and MAPbI exhibits very limited chemical durability. In this work, we report a facile colloidal synthesis method for obtaining FAPbI and FA-doped CsPbI NCs that are uniform in size (10-15 nm) and nearly cubic in shape and exhibit drastically higher robustness than their MA- or Cs-only cousins with similar sizes and morphologies. Detailed structural analysis indicated that the FAPbI NCs had a cubic crystal structure, while the FACsPbI NCs had a 3D orthorhombic structure that was isostructural to the structure of CsPbBr NCs. Bright photoluminescence (PL) with high quantum yield (QY > 70%) spanning red (690 nm, FACsPbI NCs) and near-infrared (near-IR, ca. 780 nm, FAPbI NCs) regions was sustained for several months or more in both the colloidal state and in films. The peak PL wavelengths can be fine-tuned by using postsynthetic cation- and anion-exchange reactions. Amplified spontaneous emissions with low thresholds of 28 and 7.5 μJ cm were obtained from the films deposited from FACsPbI and FAPbI NCs, respectively. Furthermore, light-emitting diodes with a high external quantum efficiency of 2.3% were obtained by using FAPbI NCs.

摘要

钙钛矿型卤铅纳米晶(NCs)[A=Cs、CHNH(甲基铵或 MA)或 CH(NH)(甲脒或 FA);X=Cl、Br、I] 最近作为多功能光子源出现,可用于从简单的光致发光下转换(例如,用于显示背光灯)到发光二极管等应用。从光谱覆盖范围来看,这些材料面临的一个艰巨挑战是如何在基于碘的组成中获得稳定的红和红外光谱区域的发射。到目前为止,红色发射的 CsPbI NCs 已经显示出延迟相变为非发光、宽带隙 1D 多晶型物的趋势,而 MAPbI 表现出非常有限的化学稳定性。在这项工作中,我们报告了一种简便的胶体合成方法,用于获得 FA 掺杂的 FAPbI 和 CsPbI NCs,它们在尺寸(10-15nm)上均匀且近立方形状,并表现出比具有相似尺寸和形态的 MA 或 Cs 同类物更高的稳健性。详细的结构分析表明,FAPbI NCs 具有立方晶体结构,而 FACsPbI NCs 具有 3D 正交结构,与 CsPbBr NCs 的结构同构。在胶体状态和薄膜中,明亮的光致发光(PL)具有高量子产率(QY>70%),覆盖红色(690nm,FACsPbI NCs)和近红外(近红外,约 780nm,FAPbI NCs)区域,可持续数月或更长时间。通过使用后合成的阳离子和阴离子交换反应,可以精细调整峰值 PL 波长。从 FACsPbI 和 FAPbI NCs 沉积的薄膜中分别获得了低阈值(28 和 7.5μJ cm)的放大自发发射。此外,使用 FAPbI NCs 获得了外量子效率为 2.3%的发光二极管。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da8f/5800405/de582bb14719/nn-2017-00116w_0001.jpg

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验