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用于液化石油气传感的高灵敏度乙二醇掺杂聚(3,4-乙撑二氧噻吩)-聚苯乙烯磺酸盐有机薄膜

Highly sensitive ethylene glycol-doped PEDOT-PSS organic thin films for LPG sensing.

作者信息

Pasha Apsar, Khasim Syed, Al-Hartomy Omar A, Lakshmi Mohana, Manjunatha K G

机构信息

Department of Physics, Ghousia College of Engineering Ramanagaram-562159 Karnataka India.

Department of Physics, Faculty of Science, University of Tabuk Tabuk 71491 Kingdom of Saudi Arabia.

出版信息

RSC Adv. 2018 May 16;8(32):18074-18083. doi: 10.1039/c8ra01061g. eCollection 2018 May 14.

DOI:10.1039/c8ra01061g
PMID:35542062
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9080499/
Abstract

In this study, for the first time we report the fabrication of low-cost ethylene glycol (EG)-doped PEDOT-PSS (poly 3,4-ethylenedioxythiophene:polystyrene sulfonate) organic thin film sensors for the detection of LPG at room temperature. The prepared thin films were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier transform infrared spectroscopy (FTIR), ultraviolet-visible (UV-Vis) spectroscopy and thermogravimetric analysis (TGA) techniques for the analysis of their structural and morphological features. The doping of EG strongly improved the conductivity of pure PEDOT-PSS films by three orders of magnitude. The gas sensing responses of pristine and doped PEDOT-PSS thin films were investigated at room temperature by fabricating a sensor device on an ITO-coated glass substrate. The gas sensing characteristics of the prepared thin films were investigated for liquified petroleum gas (LPG), dimethyl propane, methane and butane test gases. The EG-doped PEDOT-PSS thin films exhibited excellent sensitivity for all the test gases, especially towards LPG, at room temperature. The sensitivity of the doped PEDOT-PSS films was recorded to be >90% for LPG with improved response and recovery time. The stability study indicated that the sensing response of doped PEDOT-PSS thin films was highly stable over a period of 30 days. Due to enhanced sensitivity, stability and fast response and recovery times, these EG-doped PEDOT-PSS thin films can be used in gas sensor technology, especially towards the detection of LPG at room temperature.

摘要

在本研究中,我们首次报道了低成本的乙二醇(EG)掺杂聚3,4-乙撑二氧噻吩:聚苯乙烯磺酸盐(PEDOT-PSS)有机薄膜传感器的制备,用于在室温下检测液化石油气(LPG)。通过扫描电子显微镜(SEM)、原子力显微镜(AFM)、傅里叶变换红外光谱(FTIR)、紫外可见(UV-Vis)光谱和热重分析(TGA)技术对制备的薄膜进行表征,以分析其结构和形态特征。EG的掺杂使纯PEDOT-PSS薄膜的电导率提高了三个数量级。通过在涂有ITO的玻璃基板上制作传感器器件,在室温下研究了原始和掺杂的PEDOT-PSS薄膜的气敏响应。针对液化石油气(LPG)、二甲基丙烷、甲烷和丁烷测试气体,研究了制备薄膜的气敏特性。EG掺杂的PEDOT-PSS薄膜在室温下对所有测试气体都表现出优异的灵敏度,尤其是对LPG。掺杂的PEDOT-PSS薄膜对LPG的灵敏度记录为>90%,同时响应和恢复时间得到改善。稳定性研究表明,掺杂的PEDOT-PSS薄膜的传感响应在30天内高度稳定。由于灵敏度提高、稳定性好以及响应和恢复时间快,这些EG掺杂的PEDOT-PSS薄膜可用于气体传感器技术,特别是在室温下检测LPG。

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