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用于同时实现可见光透射、红外反射和微波吸收的可扩展制造超材料

Scalable-Manufactured Metamaterials for Simultaneous Visible Transmission, Infrared Reflection, and Microwave Absorption.

作者信息

Li Dong, Chen Qixiang, Huang Jinhua, Xu Hua, Lu Yuehui, Song Weijie

机构信息

School of Physical Science and Technology, Ningbo University, Ningbo 315211, China.

Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China.

出版信息

ACS Appl Mater Interfaces. 2022 Jul 14. doi: 10.1021/acsami.2c03346.

Abstract

Scalable manufacturing of metamaterials with multispectral manipulation capabilities remains highly challenging, which was generally circumvented by integrating several single-spectral metamaterials, potentially leading to complex processes, large thicknesses, and limited fabrication size. We experimentally demonstrate a standalone and scalable-manufactured multispectral metamaterial featuring simultaneous visible transmission, infrared reflection, and microwave absorption. The prepared multispectral metamaterial with an area of 255 cm exhibits a visible transmittance of 74.5% at wavelengths of 400-700 nm (the highest 80.2% at 510 nm), a thermal emissivity of 0.08 at the infrared (IR) wavelengths of 2.5-20 μm (the lowest 0.03 at 19.5 μm), and a microwave absorptance of 63.4% at frequencies of 8.2-12.4 GHz (the near-perfect 97.4% at 11.5 GHz) on average with a deep-subwavelength thickness of λ/47. The deep-subwavelength multispectral metamaterial consists of a submillimeter-thick polyethylene terephthalate dielectric spacer sandwiched by a patterned ultrathin metal and a metal mesh back-reflector with ultralow sheet resistances. Unlike the conventional optically transparent microwave absorbers made from indium tin oxides, the surface plasmonic modes can be excited within the submillimeter-thick multispectral metamaterial, bringing about the gap plasmon polaritons-induced microwave attenuation, together with the excellent visible transparency and high IR reflection/low IR emissivity. This work may inspire the designs and practical production of standalone multispectral metamaterials and benefit the protection against ubiquitous IR and microwave reconnaissance without impeding visual observation.

摘要

可扩展制造具有多光谱操纵能力的超材料仍然极具挑战性,通常通过集成几种单光谱超材料来规避这一问题,这可能导致工艺复杂、厚度大且制造尺寸受限。我们通过实验展示了一种独立且可扩展制造的多光谱超材料,其具有同时的可见光透射、红外反射和微波吸收特性。制备的面积为255平方厘米的多光谱超材料在400 - 700纳米波长处的可见光透射率为74.5%(在510纳米处最高为80.2%),在2.5 - 20微米的红外(IR)波长处的热发射率为0.08(在19.5微米处最低为0.03),在8.2 - 12.4吉赫兹频率下的微波吸收率平均为63.4%(在11.5吉赫兹处接近完美的97.4%),其厚度为深亚波长的λ/47。这种深亚波长多光谱超材料由一个亚毫米厚的聚对苯二甲酸乙二酯介电间隔层夹在一个有图案的超薄金属和一个具有超低表面电阻的金属网背反射器之间组成。与由铟锡氧化物制成的传统光学透明微波吸收器不同,表面等离子体模式可以在亚毫米厚的多光谱超材料中被激发,带来间隙等离子体激元诱导的微波衰减,同时具有出色的可见光透明度和高红外反射/低红外发射率。这项工作可能会激发独立多光谱超材料的设计和实际生产,并有利于在不阻碍视觉观察的情况下抵御无处不在的红外和微波侦察。

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