Ogbu Ikechukwu Martin, Bassani Dario M, Robert Frédéric, Landais Yannick
University of Bordeaux, Institute of Molecular Sciences (ISM), UMR-CNRS 5255, 351, Cours de la Libération, 33405 Talence Cedex, France.
Chem Commun (Camb). 2022 Aug 4;58(63):8802-8805. doi: 10.1039/d2cc03155h.
Photocatalyzed oxidative decarboxylation of oxamic acids under near-infrared irradiation using Os(bptpy)(PF) as catalyst is reported. The reaction was applied to the synthesis of urethanes and heterocyclic amides. Mechanistic studies and comparative penetration depths between the NIR and the visible light mediated processes are discussed.
报道了以Os(bptpy)(PF)为催化剂，在近红外辐射下光催化草氨酸的氧化脱羧反应。该反应应用于聚氨酯和杂环酰胺的合成。讨论了机理研究以及近红外和可见光介导过程之间的比较穿透深度。
