Occurrence and distribution of persistent organic pollutants (POPs) in the atmosphere of the Andean city of Medellin, Colombia.

Passive air sampling (PAS) was used to evaluate organochlorine pesticides, polychlorinated biphenyls, polybrominated diphenyl ethers, polybrominated biphenyl, hexabromocyclododecane, polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and perfluoroalkane substances in the atmosphere of Medellin, Colombia. PAS was carried out for three months (four quarters per year) over two consecutive years (2017 and 2018). This study allowed establishing the baseline of some pollutants in the city against which future temporal trends can be assessed. Furthermore, monitoring results suggested releases of DDT in the city or surrounding areas despite this pollutant was banned many years ago in the country. Moreover, this study evidenced the limited scope of the national laboratories to analyze persistent organic pollutants, specially brominated and fluorinated contaminants. However, there is an installed capacity to analyze organochlorine pesticide and indicator PCB in future national monitoring plans. Therefore, it is essential to realize efforts to improve the analytical capacity and increase the scope of the national laboratories. Furthermore, the PAS strategy was valuable for monitoring these pollutants in air. Finally, the results provide an overall view of persistent organic pollutants levels and represent an initial attempt to monitor and surveillance the releases of these pollutants in the city.