Yao Huifeng, Hou Jianhui
Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Polymer Physics and Chemistry, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
Angew Chem Int Ed Engl. 2022 Sep 12;61(37):e202209021. doi: 10.1002/anie.202209021. Epub 2022 Aug 10.
Single-junction organic solar cells (OSCs) have made significant progress in recent years. Innovations in material design and device optimization have improved the power conversion efficiencies to over 19 %. In this Minireview, based on recent advances, we discuss molecular design strategies to tune the absorption spectrum, energy level, and intermolecular aggregation as well as highlight the role of molecular electrostatic potential in decreasing energy loss. Then, we introduce the latest progress in four types of OSCs composed of different donor:acceptor combinations: polymer donor:small-molecule acceptor, all-polymer, all-small-molecule, and small-molecule donor:polymer acceptor. Finally, the challenges of OSCs in practical applications, including material cost, stability, and multi-function integration, are discussed.
单结有机太阳能电池(OSC)近年来取得了显著进展。材料设计和器件优化方面的创新已将功率转换效率提高到了19%以上。在这篇小型综述中,基于近期的进展,我们讨论了调节吸收光谱、能级和分子间聚集的分子设计策略,并强调了分子静电势在降低能量损失中的作用。然后,我们介绍了由不同供体:受体组合构成的四种类型的OSC的最新进展:聚合物供体:小分子受体、全聚合物、全小分子以及小分子供体:聚合物受体。最后,讨论了OSC在实际应用中的挑战,包括材料成本、稳定性和多功能集成。