Suppr超能文献

R⁴ 中硬超球柱体的位力系数:纵横比的影响。

Virial coefficients of hard hyperspherocylinders in R^{4}: Influence of the aspect ratio.

作者信息

Kulossa Markus, Marienhagen Philipp, Wagner Joachim

机构信息

Institut für Chemie, Universität Rostock, 18051 Rostock, Germany.

出版信息

Phys Rev E. 2022 Jun;105(6-1):064121. doi: 10.1103/PhysRevE.105.064121.

Abstract

We provide second- to sixth-order virial coefficients of hard hyperspherocylinders in dependence on their aspect ratio ν. Virial coefficients of an anisotropic geometry in four dimensions are calculated employing an optimized Mayer-sampling algorithm. As the second virial coefficient of a hard particle is identical to its excluded hypervolume, the numerically obtained second virial coefficients can be compared to analytical relations for the excluded hypervolume based on geometric measures of the respective, convex geometry in dependence on its aspect ratio ν.

摘要

我们给出了硬超球柱体的二阶到六阶维里系数,这些系数取决于它们的纵横比ν。利用优化的迈耶抽样算法计算了四维各向异性几何体的维里系数。由于硬粒子的二阶维里系数与其排除超体积相同,因此可以将数值获得的二阶维里系数与基于相应凸几何体几何度量且取决于其纵横比ν的排除超体积的解析关系进行比较。

相似文献

5
Virial Coefficients and Equations of State for Hard Polyhedron Fluids.硬多面体流体的维里系数和状态方程。
Langmuir. 2017 Oct 24;33(42):11788-11796. doi: 10.1021/acs.langmuir.7b02384. Epub 2017 Oct 3.

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验