Qin Zhengsheng, Gao Can, Gao Haikuo, Wang Tianyu, Dong Huanli, Hu Wenping
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China.
Sci Adv. 2022 Jul 8;8(27):eabp8775. doi: 10.1126/sciadv.abp8775.
Developing high-mobility emissive organic semiconductors with tunable colors is crucial for organic light-emitting transistors (OLETs), a pivotal component of integrated optoelectronic devices, but remains a great challenge. Here, we demonstrate a series of color-tunable, high-mobility, emissive, organic semiconductors via molecular doping with a high-mobility organic semiconductor, 2,6-diphenylanthracene, as the host. The well-matched molecular structures and sizes with efficient energy transfer between the host and guest enable the intrinsically high charge transport with tunable colors. High mobility with the highest value >2 cm V s and strong emission with photoluminescence quantum yield >15.8% are obtained for these molecular-doped organic semiconductors. Last, a large color gamut for constructed OLETs is up to 59% National Television System Committee standard, meanwhile with an extremely high current density approaching 326.4 kA cm, showing great potential for full-color smart display, organic electrically pumped lasers and other related logic circuitries.
开发具有可调节颜色的高迁移率发光有机半导体对于有机发光晶体管(OLETs)至关重要,OLETs是集成光电器件的关键组件,但仍然是一个巨大的挑战。在此,我们通过以高迁移率有机半导体2,6-二苯基蒽为主基质进行分子掺杂,展示了一系列颜色可调、高迁移率、发光的有机半导体。主体和客体之间良好匹配的分子结构和尺寸以及高效的能量转移,使得能够实现具有可调颜色的本征高电荷传输。这些分子掺杂的有机半导体具有最高值>2 cm V s的高迁移率和光致发光量子产率>15.8%的强发射。最后,构建的OLETs的大色域高达59%的国家电视系统委员会标准,同时具有接近326.4 kA cm的极高电流密度,在全彩智能显示、有机电泵浦激光器和其他相关逻辑电路方面显示出巨大潜力。