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金属催化小分子合成中基于氧化还原活性BIAN的二亚胺配体

Redox-active BIAN-based Diimine Ligands in Metal-Catalyzed Small Molecule Syntheses.

作者信息

Bernauer Josef, Pölker Jennifer, Jacobi von Wangelin Axel

机构信息

Department of Chemistry University of Hamburg Martin Luther King Pl 6 20146 Hamburg Germany.

出版信息

ChemCatChem. 2022 Jan 10;14(1):e202101182. doi: 10.1002/cctc.202101182. Epub 2021 Oct 22.

DOI:10.1002/cctc.202101182
PMID:35875682
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9298226/
Abstract

α-Diimine ligands have significantly shaped the coordination chemistry of most transition metal complexes. Among them, bis(imino)acenaphthene ligands (BIANs) have recently been matured to great versatility and applicability to catalytic reactions. Besides variations of the ligand periphery, the great versatility of BIAN ligands resides within their ability to undergo facile electronic manipulations. This review highlights key aspects of BIAN ligands in metal complexes and summarizes recent contributions of metal-BIAN catalysts to syntheses of small and functionalized organic molecules.

摘要

α-二亚胺配体显著地塑造了大多数过渡金属配合物的配位化学。其中，苊二亚胺配体（BIANs）最近已发展到具有高度的通用性，并适用于催化反应。除了配体周边的变化外，BIAN配体的高度通用性还在于它们能够进行便捷的电子调控。本综述重点介绍了金属配合物中BIAN配体的关键方面，并总结了金属-BIAN催化剂对小分子和功能化有机分子合成的最新贡献。

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