Hill Nicholas J, Vargas-Baca Ignacio, Cowley Alan H
Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI 53706, USA.
Dalton Trans. 2009 Jan 14(2):240-53. doi: 10.1039/b815079f. Epub 2008 Nov 12.
Bis(imino)acenaphthenes (BIAN) have been known for many years. However, it is only since the 1990s that such compounds have been recognized as robust ligands for the support of catalytically active transition metal centers. More recently, the unique stereoelectronic properties of the BIAN ligand class are beginning to be appreciated and exploited for some fascinating new developments in synthetic, structural and catalytic s- and p-block chemistry.
双（亚氨基）苊（BIAN）已为人所知多年。然而，直到20世纪90年代，这类化合物才被认为是用于支撑催化活性过渡金属中心的稳定配体。最近，BIAN配体类独特的立体电子性质开始得到重视，并被用于合成、结构以及主族和p区化学领域一些引人入胜的新进展中。
