双（亚氨基）苊（BIAN）配体与s-和p-族元素配位化学的最新进展。

Recent developments in the coordination chemistry of bis(imino)acenaphthene (BIAN) ligands with s- and p-block elements.

作者信息

Hill Nicholas J, Vargas-Baca Ignacio, Cowley Alan H

机构信息

Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI 53706, USA.

出版信息

Dalton Trans. 2009 Jan 14(2):240-53. doi: 10.1039/b815079f. Epub 2008 Nov 12.

DOI:10.1039/b815079f

PMID:19089002

Abstract

Bis(imino)acenaphthenes (BIAN) have been known for many years. However, it is only since the 1990s that such compounds have been recognized as robust ligands for the support of catalytically active transition metal centers. More recently, the unique stereoelectronic properties of the BIAN ligand class are beginning to be appreciated and exploited for some fascinating new developments in synthetic, structural and catalytic s- and p-block chemistry.

摘要

双（亚氨基）苊（BIAN）已为人所知多年。然而，直到20世纪90年代，这类化合物才被认为是用于支撑催化活性过渡金属中心的稳定配体。最近，BIAN配体类独特的立体电子性质开始得到重视，并被用于合成、结构以及主族和p区化学领域一些引人入胜的新进展中。