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再生聚对苯二甲酸乙二酯电纺垫的性能对其制造所用材料来源的依赖性。

The Dependence of the Properties of Recycled PET Electrospun Mats on the Origin of the Material Used for Their Fabrication.

作者信息

Kijeńska-Gawrońska Ewa, Wiercińska Katarzyna, Bil Monika

机构信息

Centre for Advanced Materials and Technologies CEZAMAT, Warsaw University of Technology, Poleczki 19, 02-822 Warsaw, Poland.

Faculty of Materials Science and Engineering, Warsaw University of Technology, Woloska 141, 02-507 Warsaw, Poland.

出版信息

Polymers (Basel). 2022 Jul 16;14(14):2881. doi: 10.3390/polym14142881.

Abstract

Plastic materials are one of the significant components of construction materials omnipresent in all areas of the industry and everyday life. One of these plastics is polyethylene terephthalate (PET). Due to its processing properties, with a simultaneous low production cost, PET has been used in many industrial applications, including the production of various types of bottles. Moreover, the high consumption of PET bottles causes the accumulation of large amounts of their waste and necessitates finding an effective way to recycle them. Electrospinning is a well-known non-complicated method for the fabrication of nonwovens from polymers and composites, which can be utilized in many fields due to their outstanding properties. In addition, it might be a promising technique for the recycling of plastic materials. Therefore, in this study, the electrospinning approach for the recycling of two types of PET bottle wastes-bottles made of virgin PET and bottles made of recycled PET (PET bottles) has been utilized, and a comparison of the properties of the obtained materials have been performed. The fibers with diameters of 1.62 ± 0.22, 1.64 ± 0.18, and 1.89 ± 0.19 have been produced from solutions made of virgin PET granulate, PET bottles, and PET bottles made of recycled bottles, respectively. Obtained fibers underwent morphological observation using a scanning electron microscope. Physico-chemical properties using FTIR, gel chromatography, and differential scanning calorimetry have been evaluated, and mechanical properties of obtained mats have been investigated. Cytotoxicity tests using the L929 mouse fibroblast cell line revealed no cytotoxicity for all tested materials.

摘要

塑料材料是建筑材料的重要组成部分之一,在工业和日常生活的各个领域都随处可见。其中一种塑料是聚对苯二甲酸乙二酯(PET)。由于其加工性能,同时生产成本较低,PET已被用于许多工业应用,包括生产各种类型的瓶子。此外,PET瓶的高消费量导致大量废弃物的积累,因此有必要找到一种有效的回收方法。静电纺丝是一种众所周知的由聚合物和复合材料制造无纺布的简单方法,由于其优异的性能,可用于许多领域。此外,它可能是一种有前途的塑料材料回收技术。因此,在本研究中,采用静电纺丝方法回收两种类型的PET瓶废料——由原生PET制成的瓶子和由回收PET制成的瓶子(PET瓶),并对所得材料的性能进行了比较。分别由原生PET颗粒、PET瓶和回收瓶制成的PET瓶的溶液制备出直径为1.62±0.22、1.64±0.18和1.89±0.19的纤维。使用扫描电子显微镜对所得纤维进行形态观察。使用傅里叶变换红外光谱仪、凝胶色谱仪和差示扫描量热法对物理化学性质进行了评估,并对所得毡垫的力学性能进行了研究。使用L929小鼠成纤维细胞系进行的细胞毒性测试表明,所有测试材料均无细胞毒性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bcd1/9322509/4608fa1d74b8/polymers-14-02881-g001.jpg

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