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基于金属离子改性牡蛎壳粉和线性低密度聚乙烯的环保型杂化复合材料抗菌活性评估

Evaluation of the Antibacterial Activity of Eco-Friendly Hybrid Composites on the Base of Oyster Shell Powder Modified by Metal Ions and LLDPE.

作者信息

Widakdo Januar, Chen Tsan-Ming, Lin Meng-Chieh, Wu Jia-Hao, Lin Tse-Ling, Yu Pin-Ju, Hung Wei-Song, Lee Kueir-Rarn

机构信息

Advanced Membrane Materials Research Center, Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 106335, Taiwan.

Carbide Division, Formosa Plastics Corporation, Taipei 105076, Taiwan.

出版信息

Polymers (Basel). 2022 Jul 25;14(15):3001. doi: 10.3390/polym14153001.

Abstract

Transforming biological waste into high-value-added materials is currently attracting extensive research interest in the medical and industrial treatment fields. The design and use of new antibacterial systems are urgently needed. In this study, we used discarded oyster shell powder (OSP) to prepare calcium oxide (CaO). CaO was mixed with silver (Ag), zinc (Zn), and copper (Cu) ions as a controlled release and antibacterial system to test the antibacterial activity. The inhibition zones of various modified metals were between 22 and 29 mm for () and between 21 and 24 mm for (). In addition, linear low-density polyethylene (LLDPE) combined with CaO and metal ion forms can be an excellent alternative to a hybrid composite. The strength modulus at 1% LLDPE to LLDPE/CaO Ag increased from 297 to 320 MPa. In addition, the antimicrobial activity of LLDPE/CaO/metal ions against E. coli had an antibacterial effect of about 99.9%. Therefore, this hybrid composite material has good potential as an antibacterial therapy and biomaterial suitable for many applications.

摘要

将生物废弃物转化为高附加值材料目前在医学和工业处理领域引起了广泛的研究兴趣。迫切需要设计和使用新的抗菌系统。在本研究中,我们使用废弃的牡蛎壳粉(OSP)制备氧化钙(CaO)。将CaO与银(Ag)、锌(Zn)和铜(Cu)离子混合作为控释抗菌系统来测试抗菌活性。各种改性金属的抑菌圈对于()在22至29毫米之间,对于()在21至24毫米之间。此外,线性低密度聚乙烯(LLDPE)与CaO和金属离子形式结合可以成为混合复合材料的极佳替代品。当LLDPE与LLDPE/CaO Ag的比例为1%时,强度模量从297 MPa增加到320 MPa。此外,LLDPE/CaO/金属离子对大肠杆菌的抗菌活性具有约99.9%的抗菌效果。因此,这种混合复合材料作为抗菌治疗和适用于多种应用的生物材料具有良好的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7aac/9332488/8379aa7d22be/polymers-14-03001-g001.jpg

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