负载于多孔有机聚合物上的钯作为用于交叉偶联反应的多相可回收催化剂。
Palladium Supported on Porous Organic Polymer as Heterogeneous and Recyclable Catalyst for Cross Coupling Reaction.
机构信息
Institute of Agricultural Products Processing, Henan Academy of Agricultural Sciences, Zhengzhou 450002, China.
College of Chemistry and Chemical Engineering, Henan University of Technology, Lianhua Street 100, Zhengzhou 450001, China.
出版信息
Molecules. 2022 Jul 26;27(15):4777. doi: 10.3390/molecules27154777.
Palladium immobilized on an amide and ether functionalized porous organic polymer (Pd@AEPOP) is reported to be an effective heterogeneous catalyst for the Heck cross-coupling reaction of aryl iodides with styrene for the synthesis of diphenylethene derivatives. Excellent yields can be obtained using a 0.8 mol% Pd catalyst loading under the optimized reaction condition. The heterogeneous Pd@AEPOP catalyst can also be applied on the Suzuki reaction and the reduction of nitroarene.
报道了一种固载在酰胺和醚功能化多孔有机聚合物上的钯（Pd@AEPOP）催化剂，可有效用于芳基碘与苯乙烯的 Heck 交叉偶联反应，以合成二苯乙烯衍生物。在优化的反应条件下，使用 0.8 mol%Pd 催化剂负载量即可获得优异的产率。该负载型 Pd@AEPOP 催化剂还可应用于 Suzuki 反应和硝基芳烃的还原。
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