碘催化利用邻苯二酚、醋酸铵和烯烃/炔烃/酮类进行苯并恶唑的合成及碳-碳和碳-氧键断裂。
Iodine-catalyzed synthesis of benzoxazoles using catechols, ammonium acetate, and alkenes/alkynes/ketones C-C and C-O bond cleavage.
作者信息
Aboonajmi Jasem, Panahi Farhad, Hosseini Mina Aali, Aberi Mahdi, Sharghi Hashem
机构信息
Department of Chemistry, College of Sciences, Shiraz University Shiraz 71454 Iran
Department of Chemical and Materials Engineering, Faculty of Shahid Rajaee, Technical and Vocational University (TVU) Shiraz Branch Shiraz Iran.
出版信息
RSC Adv. 2022 Jul 21;12(32):20968-20972. doi: 10.1039/d2ra03340b. eCollection 2022 Jul 14.
An efficient metal-free synthesis strategy of benzoxazoles was developed coupling catechols, ammonium acetate, and alkenes/alkynes/ketones. The developed methodology represents an operationally simple, one-pot and large-scale procedure for the preparation of benzoxazole derivatives using molecular iodine as the catalyst.
开发了一种高效的无金属合成苯并恶唑的策略，该策略将邻苯二酚、醋酸铵与烯烃/炔烃/酮类偶联。所开发的方法是一种操作简单、一锅法且可大规模制备苯并恶唑衍生物的方法，使用分子碘作为催化剂。
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