Quantitative Analysis of Routine Chemical Constituents of Tobacco Based on Thermogravimetric Analysis.

As the most basic indexes to evaluate the quality of tobacco, the contents of routine chemical constituents in tobacco are mainly detected by continuous-flow analysis at present. However, this method suffers from complex operation, time consumption, and environmental pollution. Thus, it is necessary to establish a rapid accurate detection method. Herein, different from the ongoing research studies that mainly chose near-infrared spectroscopy as the information source for quantitative analysis of chemical components in tobacco, we proposed for the first time to use the thermogravimetric (TG) curve to characterize the chemical composition of tobacco. The quantitative analysis models of six routine chemical constituents in tobacco, including total sugar, reducing sugar, total nitrogen, total alkaloids, chlorine, and potassium, were established by the combination of TG curve and partial least squares algorithm. The accuracy of the model was confirmed by the value of root mean square error for prediction. The models can be used for the rapid accurate analysis of compound contents. Moreover, we performed an in-depth analysis of the chemical mechanism revealed by the result of the quantitative model, namely, the regression coefficient, which reflected the correlation degree between the six chemicals and different stages of the tobacco thermal decomposition process.