Li Cheng-Kun, Tao Ze-Kun, Shoberu Adedamola, Zhang Wei, Zou Jian-Ping
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University, Suzhou, Jiangsu 215123, China.
Department of Chemistry, University of Massachusetts Boston, Boston, Massachusetts 02125, United States.
Org Lett. 2022 Aug 19;24(32):6083-6087. doi: 10.1021/acs.orglett.2c02454. Epub 2022 Aug 11.
A Cu-catalyzed cross-coupling of alkyl- and phosphorus-centered radicals for C(sp)-P bond formation is introduced. Diacyl peroxides, generated in situ from aliphatic acids and HO, serve as a source for alkyl radicals and also an initiator for the generation of phosphorus radicals from H-P(O) compounds.
介绍了一种用于形成C(sp)-P键的铜催化的烷基自由基与磷中心自由基的交叉偶联反应。由脂肪酸和HO原位生成的二酰基过氧化物作为烷基自由基的来源，同时也是从H-P(O)化合物生成磷自由基的引发剂。
