硫醇-烯加成点击反应在有机硅化合物化学中的应用：经典硅氢化反应的替代方法还是补充方法？

The Use of the Thiol-Ene Addition Click Reaction in the Chemistry of Organosilicon Compounds: An Alternative or a Supplement to the Classical Hydrosilylation?

作者信息

Krizhanovskiy Ilya, Temnikov Maxim, Kononevich Yuriy, Anisimov Anton, Drozdov Fedor, Muzafarov Aziz

机构信息

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119334, Russia.

Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow 117393, Russia.

出版信息

Polymers (Basel). 2022 Jul 29;14(15):3079. doi: 10.3390/polym14153079.

This review presents the main achievements in the use of the thiol-ene reaction in the chemistry of silicones. Works are considered, starting from monomers and ending with materials.The main advantages and disadvantages of this reaction are demonstrated using various examples. A critical analysis of the use of this reaction is made in comparison with the hydrosilylation reaction.