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硫醇-烯加成点击反应在有机硅化合物化学中的应用：经典硅氢化反应的替代方法还是补充方法？

The Use of the Thiol-Ene Addition Click Reaction in the Chemistry of Organosilicon Compounds: An Alternative or a Supplement to the Classical Hydrosilylation?

作者信息

Krizhanovskiy Ilya, Temnikov Maxim, Kononevich Yuriy, Anisimov Anton, Drozdov Fedor, Muzafarov Aziz

机构信息

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119334, Russia.

Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow 117393, Russia.

出版信息

Polymers (Basel). 2022 Jul 29;14(15):3079. doi: 10.3390/polym14153079.

DOI:10.3390/polym14153079
PMID:35956590
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9370781/
Abstract

This review presents the main achievements in the use of the thiol-ene reaction in the chemistry of silicones. Works are considered, starting from monomers and ending with materials.The main advantages and disadvantages of this reaction are demonstrated using various examples. A critical analysis of the use of this reaction is made in comparison with the hydrosilylation reaction.

摘要

本综述介绍了硅氧烷化学中硫醇-烯反应应用的主要成果。所考虑的研究工作从单体开始，以材料结束。通过各种实例展示了该反应的主要优点和缺点。与硅氢加成反应相比，对该反应的应用进行了批判性分析。

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